Russian Journal of Coordination Chemistry

, Volume 42, Issue 2, pp 81–84 | Cite as

Crystal structure and magnetic properties of binuclear copper(II) complex with 2-N-(phenylhydrazono)-3-((ethyl-2-olato)imino)-1-phenyl-1,2,3-butanetrione

  • L. D. Popov
  • S. I. Levchenkov
  • I. N. Shcherbakov
  • V. V. Tkachev
  • G. V. Shilov
  • Yu. P. Tupolova
  • D. S. Samorodnyaya
  • E. V. Ivannikova
  • V. V. Lukov
  • V. A. Kogan
Article

Abstract

The binuclear copper(II) complex based on azomethine, being a condensation product of 2-aminoethanol with 1-phenyl-1,2,3-butanetrione phenylhydrazone, is structurally characterized (CIF file CCDC 1059996). The structure is compared with the structure of an analog containing the axially coordinated pyridine molecule. The influence of the axial coordination of pyridine on the magnetic exchange interaction is studied by the DFT method in the broken symmetry approach.

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Copyright information

© Pleiades Publishing, Ltd. 2016

Authors and Affiliations

  • L. D. Popov
    • 1
  • S. I. Levchenkov
    • 2
  • I. N. Shcherbakov
    • 1
  • V. V. Tkachev
    • 3
  • G. V. Shilov
    • 3
  • Yu. P. Tupolova
    • 1
  • D. S. Samorodnyaya
    • 1
  • E. V. Ivannikova
    • 1
  • V. V. Lukov
    • 1
  • V. A. Kogan
    • 1
  1. 1.Southern Federal UniversityRostov-on-DonRussia
  2. 2.Southern Scientific CenterRussian Academy of SciencesRostov-on-DonRussia
  3. 3.Institute of Problems of Chemical PhysicsRussian Academy of SciencesChernogolovka, Moscow oblastRussia

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