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Binuclear dysprosium(III) complex with 2,6-diformyl-4-tert-butylphenol bisphthalazinylhydrazone: Crystal structure and magnetic properties

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Abstract

The Dy(III) binuclear complex with N4O-donor 2,6-diformyl-4-tert-butylphenol bis-1′-phthalazinylhydrazone (H3L) of the composition [Dy2(H2L)3](NO3)3 · 3C2H5OH (CIF file CCDC 1048418) is synthesized and structurally characterized. In the complex cation [Dy2(H2L)3]3+, ligands H2L− form a three-blade helix around the Dy(III) ions. Both right-side (Δ configuration) and left-side (Λ) helicates are presented in crystal in an equimolar ratio. The magnetic properties of the complex are studied.

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Authors and Affiliations

  1. Southern Scientific Center, Russian Academy of Sciences, Rostov-on-Don, Russia

    S. I. Levchenkov

  2. Southern Federal University, Rostov-on-Don, 344104, Russia

    L. D. Popov, S. S. Beloborodov, I. N. Shcherbakov, Yu. P. Tupolova, V. V. Lukov & V. A. Kogan

  3. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Leninskii pr. 31, Moscow, 119991, Russia

    G. G. Aleksandrov

Authors
  1. S. I. Levchenkov
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  2. L. D. Popov
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  3. S. S. Beloborodov
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  4. I. N. Shcherbakov
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  5. G. G. Aleksandrov
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  6. Yu. P. Tupolova
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  7. V. V. Lukov
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  8. V. A. Kogan
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Corresponding author

Correspondence to S. I. Levchenkov.

Additional information

Original Russian Text © S.I. Levchenkov, L.D. Popov, S.S. Beloborodov, I.N. Shcherbakov, G.G. Aleksandrov, Yu.P. Tupolova, V.V. Lukov, V.A. Kogan, 2015, published in Koordinatsionnaya Khimiya, 2015, Vol. 41, No. 12, pp. 756–761.

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Levchenkov, S.I., Popov, L.D., Beloborodov, S.S. et al. Binuclear dysprosium(III) complex with 2,6-diformyl-4-tert-butylphenol bisphthalazinylhydrazone: Crystal structure and magnetic properties. Russ J Coord Chem 41, 823–828 (2015). https://doi.org/10.1134/S1070328415120040

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  • DOI: https://doi.org/10.1134/S1070328415120040

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