Russian Journal of Coordination Chemistry

, Volume 41, Issue 12, pp 823–828

Binuclear dysprosium(III) complex with 2,6-diformyl-4-tert-butylphenol bisphthalazinylhydrazone: Crystal structure and magnetic properties

  • S. I. Levchenkov
  • L. D. Popov
  • S. S. Beloborodov
  • I. N. Shcherbakov
  • G. G. Aleksandrov
  • Yu. P. Tupolova
  • V. V. Lukov
  • V. A. Kogan
Article
  • 48 Downloads

Abstract

The Dy(III) binuclear complex with N4O-donor 2,6-diformyl-4-tert-butylphenol bis-1′-phthalazinylhydrazone (H3L) of the composition [Dy2(H2L)3](NO3)3 · 3C2H5OH (CIF file CCDC 1048418) is synthesized and structurally characterized. In the complex cation [Dy2(H2L)3]3+, ligands H2L form a three-blade helix around the Dy(III) ions. Both right-side (Δ configuration) and left-side (Λ) helicates are presented in crystal in an equimolar ratio. The magnetic properties of the complex are studied.

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Copyright information

© Pleiades Publishing, Ltd. 2015

Authors and Affiliations

  • S. I. Levchenkov
    • 1
  • L. D. Popov
    • 2
  • S. S. Beloborodov
    • 2
  • I. N. Shcherbakov
    • 2
  • G. G. Aleksandrov
    • 3
  • Yu. P. Tupolova
    • 2
  • V. V. Lukov
    • 2
  • V. A. Kogan
    • 2
  1. 1.Southern Scientific CenterRussian Academy of SciencesRostov-on-DonRussia
  2. 2.Southern Federal UniversityRostov-on-DonRussia
  3. 3.Kurnakov Institute of General and Inorganic ChemistryRussian Academy of SciencesMoscowRussia

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