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Anion-directed assembly of two AgI complexes based on 2,2'-(4H-1,2,4-triazole-3,4-diyl)dipyridine

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Abstract

Reaction of the Ag+ ions with 2,2'-(4H-1,2,4-triazole-3,4-diyl)dipyridine (L22) in the presence of NO -3 and CH3SO -3 , respectively, affords two silver(I) coordination compounds, namely {[Ag3(NO3)2(C12H9N5)2](NO3)]} n (I) and [Ag(CH3SO3)(C12H9N5)]2 (II). Both complexes have been characterized by single-crystal X-ray diffraction (CIF file CCDC nos. 1051589 (I) and 1051590 (II)). In complex I, the adjacent metal centers are interconnected via L22 ligands to afford a 1D coordination chain. Complex II shows the discrete cage-like binuclear coordination pattern with the Ag···Ag distance of 4.358(1) Å.

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Authors and Affiliations

  1. College of Chemistry, Tianjin Key Laboratory of Structure and Performance for Functional Molecules, MOE Key Laboratory of Inorganic-OrganicHybrid Functional Material Chemistry, Tianjin Normal University, Tianjin, 300387, P. R. China

    B. L. Liu, M. Z. Li, C. P. Li & J. Chen

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  1. B. L. Liu
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  2. M. Z. Li
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  3. C. P. Li
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  4. J. Chen
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Correspondence to J. Chen.

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Liu, B.L., Li, M.Z., Li, C.P. et al. Anion-directed assembly of two AgI complexes based on 2,2'-(4H-1,2,4-triazole-3,4-diyl)dipyridine. Russ J Coord Chem 41, 695–700 (2015). https://doi.org/10.1134/S1070328415100048

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  • DOI: https://doi.org/10.1134/S1070328415100048

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