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A double complex Cd(II) salt containing the Keggin polyoxoanion and the supramolecular cation of the [amide…H…amide]+ type

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Abstract

The complex [H(DMFA)2]2[Cd(DMFA)6][SiW12O40] (I) was obtained by a reaction between H4[SiW12O40], CdI2, and AgNO3 in N,N-dimethylformamide (DMF) and characterized by X-ray diffraction (CIF file CCDC No. 1041227). Structure I is made up of the complex cations [Cd(DMF)6]2+, the Keggin polyoxoanions [SiW12O40]4–, and the dimeric cations [DMF...H...DMF]+, in which two DMF molecules are linked by a short hydrogen bond (O...O, 2.39(2) Å). The cations of this type were compared with similar dimeric cations containing the fragment {amide...H...amide}.

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Authors and Affiliations

  1. Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia

    S. A. Adonin, A. I. Smolentsev, M. N. Sokolov & V. P. Fedin

  2. Novosibirsk State University, Novosibirsk, Russia

    S. A. Adonin, L. I. Udalova, A. I. Smolentsev, M. N. Sokolov & V. P. Fedin

Authors
  1. S. A. Adonin
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  2. L. I. Udalova
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  3. A. I. Smolentsev
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  4. M. N. Sokolov
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  5. V. P. Fedin
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Correspondence to S. A. Adonin.

Additional information

Original Russian Text © S.A. Adonin, L.I. Udalova, A.I. Smolentsev, M.N. Sokolov, V.P. Fedin, 2015, published in Koordinatsionnaya Khimiya, 2015, Vol. 41, No. 10, pp. 579–583.

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Adonin, S.A., Udalova, L.I., Smolentsev, A.I. et al. A double complex Cd(II) salt containing the Keggin polyoxoanion and the supramolecular cation of the [amide…H…amide]+ type. Russ J Coord Chem 41, 633–637 (2015). https://doi.org/10.1134/S1070328415100012

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  • DOI: https://doi.org/10.1134/S1070328415100012

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