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Reaction of ferrocenyl triselenide with tris(triphenylphosphine)platinum

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Abstract

The reaction of ferrocenyl triselenide, Fe(C5H4)2Se3, with Pt(PPh3)3 is accompanied by elimination of one mole of SePPh3 and gives a dimeric platinum(II) chelate complex with bridging selenium atoms, [Fe(µ-C5H4Se)2Pt(PPh3)]2, which was characterized by X-ray diffraction (CIF file CCDC no. 1055075).

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Authors and Affiliations

  1. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Leninskii pr. 31, Moscow, 117907, Russia

    I. V. Skabitskii, Yu. V. Torubaev & A. A. Pasynskii

Authors
  1. I. V. Skabitskii
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  2. Yu. V. Torubaev
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  3. A. A. Pasynskii
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Correspondence to A. A. Pasynskii.

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Original Russian Text © I.V. Skabitskii, Yu.V. Torubaev, A.A. Pasynskii, 2015, published in Koordinatsionnaya Khimiya, 2015, Vol. 41, No. 10, pp. 600–603.

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Skabitskii, I.V., Torubaev, Y.V. & Pasynskii, A.A. Reaction of ferrocenyl triselenide with tris(triphenylphosphine)platinum. Russ J Coord Chem 41, 654–657 (2015). https://doi.org/10.1134/S1070328415090043

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  • DOI: https://doi.org/10.1134/S1070328415090043

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