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cis-Di-µ-chlorobis{(1S,4S)-2-[benzylimino]-7,7-dimethylbicyclo[2.2.1]heptylmethyl-C,N}dipalladium(II) and trans-dichlorobis{(1S,4S)-2-[benzylimino]-1,7,7-trimethylbicyclo[2.2.1]heptane-N}palladium(II): Syntheses and structural studies

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Abstract

Enantiomerically pure palladium complexes of different compositions, binuclear palladacycle containing the (sp 3)C–Pd bond (I) and mononuclear coordination palladium compound (II), are synthesized and studied by X-ray diffraction analysis. In complex I, the cyclopalladated ligands are in the cis position (CIF file CCDC no. 1049805 (I)). In compound II, the ligands coordinated through the monodentate mode occupy the trans position (CIF file CCDC no. 1049806 (II)).

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References

  1. Dupont, J., Consorti, C.S., and Spencer, J., Chem. Rev., 2005, no. 105, p. 2527.

    Article  CAS  Google Scholar 

  2. Dunina, V.V. and Zykov, P., Russ. Chem. Rev., 2011, no. 80, p. 51.

    Article  CAS  Google Scholar 

  3. Troitskaya, L.L., Starikova, Z.A., Demeshchik, T.V., and Sokolov, V.I., Russ. Chem. Bull., 1999, vol. 48, p. 1738.

    Article  CAS  Google Scholar 

  4. Dunina, V.V., Razmyslova, E.D., Gorunova, O.N., et al., Tetrahedron: Asymmetry, 2003, vol. 14, p. 2331.

    Article  CAS  Google Scholar 

  5. Chew, R.J., Huang, Y., Li, Y., et al, Adv. Synth. Catal., 2013, vol. 355, p. 1403.

    Article  CAS  Google Scholar 

  6. Lu, J., Ye, J., and Duan, W.-L., Org. Lett., 2013, vol. 15, p. 5016.

    Article  CAS  Google Scholar 

  7. Hyodo, K., Nakamura, S., and Shibata, N., Angew. Chem., Int. Ed. Engl., 2012, vol. 51, p. 10337.

    Article  CAS  Google Scholar 

  8. Weber, V.M., Jautze, S., Frey, W., and Peters, R., Chem.-Eur. J., 2012, vol. 18, p. 14792.

    Article  CAS  Google Scholar 

  9. Chooi, S.Y.M., Leung, P.H., Lim, C.C., et al., Tetrahedron: Asymmetry, 1992, vol. 3, p. 529.

    Article  CAS  Google Scholar 

  10. Bohm, A. and Seebach, D., Helv. Chim. Acta, 2000, vol. 83, p. 3262.

    Article  CAS  Google Scholar 

  11. Dunina, V.V., Gorunova, O.N., Livantsov, M.V., and Grishin, Y.K., Tetrahedron: Asymmetry, 2000, vol. 11, p. 2907.

    Article  CAS  Google Scholar 

  12. Figge, A., Altenbach, H.J., Brauer, D.J., and Tielmann, P., Tetrahedron: Asymmetry, 2002, vol. 13, p. 137.

    Article  CAS  Google Scholar 

  13. Duran, E., Gordo, E., Granell, J., et al., Tetrahedron: Asymmetry, 2001, vol. 12, p. 1987.

    Article  CAS  Google Scholar 

  14. Gur’eva, Ya. Frolova, L.L., et al., Russ. J. Gen. Chem., 2012, vol. 82, p. 1117.

    Google Scholar 

  15. Sheldrick, G.M., Acta Crystallogr., Sect. A: Found. Crystallogr., 2008, vol. 64, p. 112.

    Article  CAS  Google Scholar 

  16. Malik, K.M.A. and Newman, P.D., Dalton Trans., 2003, p. 3516.

    Google Scholar 

  17. Watson, A.A., House, D.A., and Steel, P.J., J. Organomet. Chem., 1986, vol. 311, p. 387.

    Article  CAS  Google Scholar 

  18. Dickmu, G.C., Stahl, L., Smoliakova, I.P., J. Organomet. Chem., 2014, vol. 756, p. 27.

    Article  CAS  Google Scholar 

  19. Gorunova, O.N., Keuseman, K.J., Goebel, B.M., et al., J. Organomet. Chem., 2004, vol. 689, p. 2382.

    Article  CAS  Google Scholar 

  20. Schildbach, D., Arroyo, M., and Lehmen, K., Organometallics, 2004, vol. 23, p. 3228.

    Article  CAS  Google Scholar 

Download references

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Authors and Affiliations

  1. Syktyvkar State University, Syktyvkar, Russia

    O. A. Zalevskaya

  2. Institute of Chemistry, Komi Research Center, Ural Branch, Russian Academy of Sciences, Syktyvkar, Russia

    Ya. A. Gur’eva & A. V. Kuchin

  3. Postovskii Institute of Organic Synthesis, Ural Branch, Russian Academy of Sciences, Yekaterinburg, Russia

    P. A. Slepukhin

Authors
  1. O. A. Zalevskaya
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  2. Ya. A. Gur’eva
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  3. P. A. Slepukhin
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  4. A. V. Kuchin
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Corresponding author

Correspondence to Ya. A. Gur’eva.

Additional information

Original Russian Text © O.A. Zalevskaya, Ya.A. Gur’eva, P.A. Slepukhin, A.V. Kuchin, 2015, published in Koordinatsionnaya Khimiya, 2015, Vol. 41, No. 8, pp. 496–500.

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Zalevskaya, O.A., Gur’eva, Y.A., Slepukhin, P.A. et al. cis-Di-µ-chlorobis{(1S,4S)-2-[benzylimino]-7,7-dimethylbicyclo[2.2.1]heptylmethyl-C,N}dipalladium(II) and trans-dichlorobis{(1S,4S)-2-[benzylimino]-1,7,7-trimethylbicyclo[2.2.1]heptane-N}palladium(II): Syntheses and structural studies. Russ J Coord Chem 41, 532–536 (2015). https://doi.org/10.1134/S1070328415080114

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  • DOI: https://doi.org/10.1134/S1070328415080114

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