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Solvolthermal synthesis, structure, and properties of a novel dinuclear zinc(II) complex

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Abstract

A novel centrosymmetric dinuclear zinc(II) complex, [Zn2L2], was prepared from 2-bromo-6-[(3-cyclohexylaminopropylimino)methyl]phenol (H2L), 3,5-dichlorosalicylaldehyde, and zinc acetate under solvolthermal conditions. There occurs a rarely-seen 1,3-hydride shift reaction during the process. Structure of [Zn2L2] has been characterized by elemental analysis, IR spectra, and single crystal X-ray diffraction (CIF file CCDC no. 956057). The Zn⋯Zn separation is 3.163(1)°. Each Zn atom in the complex is in a trigonal-bipyramidal coordination. Thermal stability and fluorescence property of [Zn2L2] were studied. The complex displays intraligand π-π* fluorescence and can potentially serve as photoactive material.

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Authors and Affiliations

  1. Department of Public Subject, Shangqiu Medical College, Shangqiu, 476100, P.R. China

    N. Wang

  2. School of Chemistry and Chemical Engineering, Shangqiu Normal University, Shangqiu, 476000, P.R. China

    X. Y. Qiu

Authors
  1. N. Wang
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  2. X. Y. Qiu
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Correspondence to N. Wang.

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Wang, N., Qiu, X.Y. Solvolthermal synthesis, structure, and properties of a novel dinuclear zinc(II) complex. Russ J Coord Chem 41, 410–414 (2015). https://doi.org/10.1134/S1070328415060093

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  • DOI: https://doi.org/10.1134/S1070328415060093

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