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Metal complexes of azomethine compounds bearing an azo group in the amine fragment: Syntheses, structures, and properties

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Abstract

New complexes of Cu(II), Co(II), Ni(II), and Zn(II) with 1-phenyl-3-methyl-4-(4-phenylazophenylaminomethylene)pyrazol-5-one (HL1) and 1-phenyl-3-methyl-4-[4-methyl-2-(4-methylphenylazo)phenylaminomethylene]pyrazol-5-one (HL2) are synthesized using chemical and electrochemical methods and characterized by IR spectroscopy, 1H NMR spectroscopy, X-ray absorption spectroscopy, X-ray diffraction analysis, and magnetic measurements. All complexes are mononuclear. The structures of HL2 and related cobalt complex are determined by X-ray diffraction analysis (CIF files CCDC nos. 1028957 and 1035847, respectively).

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Authors and Affiliations

  1. Research Institute of Physical and Organic Chemistry, Southern Federal University, Rostov-on-Don, Russia

    A. S. Burlov, S. A. Mashchenko, Yu. V. Koshchienko, A. I. Uraev, D. A. Garnovskii & E. V. Korshunova

  2. Research Institute of Physics, Southern Federal University, Rostov-on-Don, Russia

    V. G. Vlasenko

  3. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, ul. Vavilova 28, Moscow, 119991, Russia

    K. A. Lysenko & Ya. V. Zubavichus

  4. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Leninskii pr. 31, Moscow, 119991, Russia

    A. S. Antsyshkina, G. G. Sadikov & V. S. Sergienko

  5. Kurchatov Institute Russian Research Center, pl. Kurchatova 1, Moscow, 123182, Russia

    Ya. V. Zubavichus

  6. Southern Scientific Center, Russian Academy of Sciences, Rostov-on-Don, Russia

    D. A. Garnovskii & S. I. Levchenkov

Authors
  1. A. S. Burlov
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  2. S. A. Mashchenko
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  3. V. G. Vlasenko
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  4. K. A. Lysenko
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  5. A. S. Antsyshkina
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  6. G. G. Sadikov
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  7. V. S. Sergienko
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  8. Yu. V. Koshchienko
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  9. Ya. V. Zubavichus
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  10. A. I. Uraev
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  11. D. A. Garnovskii
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  12. E. V. Korshunova
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  13. S. I. Levchenkov
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Corresponding author

Correspondence to A. S. Burlov.

Additional information

Original Russian Text © A.S. Burlov, S.A. Mashchenko, V.G. Vlasenko, K.A. Lysenko, A.S. Antsyshkina, G.G. Sadikov, V.S. Sergienko, Yu.V. Koshchienko, Ya.V. Zubavichus, A.I. Uraev, D.A. Garnovskii, E.V. Korshunova, S.I. Levchenkov, 2015, published in Koordinatsionnaya Khimiya, 2015, Vol. 41, No. 6, pp. 346–356.

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Burlov, A.S., Mashchenko, S.A., Vlasenko, V.G. et al. Metal complexes of azomethine compounds bearing an azo group in the amine fragment: Syntheses, structures, and properties. Russ J Coord Chem 41, 376–386 (2015). https://doi.org/10.1134/S1070328415060019

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  • DOI: https://doi.org/10.1134/S1070328415060019

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