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Synthesis, structure, and magnetic property of a 3D supramolecular Gd(III) coordination polymer with 4,4′-sulfonyldibenzoic acid ligands

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Abstract

A new coordination polymer [Gd(Sfdb)(NO3)(DMF)2] · 2H2O (Sfdb = 4,4′-sulfonyldibenzoic acid) has been synthesized under hydrothermal conditions and characterized by elemental analysis, IR, TG and single-crystal X-ray diffraction (CIF file CCDC no. 1023460). The X-ray diffraction analysis shows that I (C20H24N3O12SGd) crystallizes in the monoclinic crystal system, which reveals that I is a 3D supramolecular framework assembled by the intermolecular hydrogen bonds. Moreover, the magnetic studies of I showed that there exist antiferromagnetic interactions between the Gd(III) centres. The unit cell parameters for I: a = 33.453(3), b = 10.5469(10), c = 18.7895(18) Å, β = 123.7670(10)°, V = 5511.0(9) Å3, Z = 8.

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Authors and Affiliations

  1. College of Chemistry, Liaoning University, Shenyang, 110036, P.R. China

    X. N. Zhang & Z. B. Han

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  1. X. N. Zhang
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  2. Z. B. Han
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Correspondence to Z. B. Han.

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Zhang, X.N., Han, Z.B. Synthesis, structure, and magnetic property of a 3D supramolecular Gd(III) coordination polymer with 4,4′-sulfonyldibenzoic acid ligands. Russ J Coord Chem 41, 334–338 (2015). https://doi.org/10.1134/S1070328415050097

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  • DOI: https://doi.org/10.1134/S1070328415050097

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