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The second example for a cubane-like copper(II) complex in a series of N-hydroxyalkyl β-alanine derivatives

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Abstract

A new tetranuclear cubane-like copper(II) complex [Cu4(HL1)4] based on N-(1,1-dihydroxymethyl)ethyl-βalanine (H3L1) is synthesized. Its structure is studied by X-ray diffraction analysis (CIF file CCDC 1020735). In the crystal structure of the complex, the copper atoms are joined into tetrahedra with the distances Cu⋯Cu 3.139–3.456 Å supplemented to cubanes by the μ3-bridging oxygen atoms of the hydroxymethyl groups. The coordination environment of each metal center is a distorted octahedron. The (HL1)2− ligand is doubly protonated and performs the hexadentate chelate-(μ3-bridging) function to form the alkoxocarboxylate chelate of copper(II).

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Authors and Affiliations

  1. Ural Federal University Named after the First President of Russia Yeltsin, Yekaterinburg, Russia

    M. I. Ul’yanova, S. A. Baskakova, T. V. Aksenova & A. V. Pestov

  2. Postovskii Institute of Organic Synthesis, Ural Branch, Russian Academy of Sciences, Yekaterinburg, Russia

    P. A. Slepukhin & A. V. Pestov

Authors
  1. M. I. Ul’yanova
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  2. S. A. Baskakova
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  3. T. V. Aksenova
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  4. P. A. Slepukhin
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  5. A. V. Pestov
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Corresponding author

Correspondence to A. V. Pestov.

Additional information

Original Russian Text © M.I. Ul’yanova, S.A. Baskakova, T.V. Aksenova, P.A. Slepukhin, A.V. Pestov, 2015, published in Koordinatsionnaya Khimiya, 2015, Vol. 41, No. 4, pp. 213–219.

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Ul’yanova, M.I., Baskakova, S.A., Aksenova, T.V. et al. The second example for a cubane-like copper(II) complex in a series of N-hydroxyalkyl β-alanine derivatives. Russ J Coord Chem 41, 240–246 (2015). https://doi.org/10.1134/S1070328415040090

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  • DOI: https://doi.org/10.1134/S1070328415040090

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