Abstract
Samples of silicon nanocrystals with surfaces modified by various organic ligands are synthesized. Their IR spectra are studied and interpreted. The quantum-chemical calculations of the vibrational spectra of model compounds are performed. A chemical bond between the ligands and nanosilicon particles is concluded on the basis of a comparison of the experimental and calculated data.
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Original Russian Text © V.M. Senyavin, E.D. Feklichev, V.N. Zakharov, G.M. Kuramshina, L.A. Aslanov, 2015, published in Koordinatsionnaya Khimiya, 2015, Vol. 41, No. 4, pp. 195–202.
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Senyavin, V.M., Feklichev, E.D., Zakharov, V.N. et al. Silicon nanocrystals stabilized by organic radicals: Spectral and theoretical study. Russ J Coord Chem 41, 221–229 (2015). https://doi.org/10.1134/S1070328415040065
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DOI: https://doi.org/10.1134/S1070328415040065