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Hydrothermal syntheses, crystal structures, and magnetic properties of three manganese(II) complexes based on 4′-substituted 2,2′:6′,2″-terpyridine ligands

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Abstract

Three manganese coordination compounds, [Mn(Meophtpy)2] · 2ClO4 (Meophtpy = 4′-(4-methoxylphenyl)-2,2′:6′,2″-terpyridine) (I), [Mn(Ftpy)2](ClO4)2 (Ftpy = 4′-(2-furyl)-2,2′:6′,2″-terpyridine) (II) and [Mn(m-ClPhtpy)2] · 2ClO4 (m-ClPhtpy = 4′-(3-chlorophenyl)-2,2′:6′,2″-terpyridine) (III), have been synthesized by hydrothermal methods and characterized by IR, elemental analysis, powder and single-crystal X-ray diffraction analyses (CIF files CCDC nos. 945032 (I), 945033 (II), 945034 (III)). In most cases, the face-to-face interactions between pyridyl rings or phenyl rings facilitate the construction of 3D network in the crystal for all three complexes. The magnetic properties of three complexes have been investigated.

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Authors and Affiliations

  1. Key Laboratory of Functional Organometallic Materials of Hunan Province College, Department of Chemistry and Materials Science, Hengyang Normal University, Hengyang, 421008, P.R. China

    W. W. Fu, M. S. Chen, W. Li, Y. Liu, F. X. Zhang & D. Z. Kuang

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  1. W. W. Fu
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  2. M. S. Chen
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  3. W. Li
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  4. Y. Liu
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  5. F. X. Zhang
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  6. D. Z. Kuang
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Correspondence to W. W. Fu.

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Fu, W.W., Chen, M.S., Li, W. et al. Hydrothermal syntheses, crystal structures, and magnetic properties of three manganese(II) complexes based on 4′-substituted 2,2′:6′,2″-terpyridine ligands. Russ J Coord Chem 41, 247–254 (2015). https://doi.org/10.1134/S1070328415040028

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  • DOI: https://doi.org/10.1134/S1070328415040028

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