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Binuclear copper(II) complex with bis(azomethine) based on 1,3-diaminopropan-2-ol and 4-hydroxy-3-formylcoumarin: Crystal structure and magnetic properties

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Abstract

The binuclear copper(II) complex [Cu2(L)(Mp)(H2O)((CH3)2SO)] (Mp is 6-methoxypurinate anion) with the heterocyclic azomethine ligand, which is the condensation product of 1,3-diaminopropan-2-ol and 4-hydroxy-3-formylcoumarin (H3L), is synthesized and structurally characterized (CIF file CCDC no. 982199). The temperature dependence of the magnetic susceptibility is measured and shows a significant exchange interaction of the antiferromagnetic type (2J = −348 cm−1) in the compound. This sharply distinguishes the new complex from the earlier studied compounds with a similar exchange fragment characteristic of the ferromagnetic exchange. The antiferromagnetic exchange parameter is calculated by the quantum-chemical DFT method in the broken symmetry approximation.

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References

  1. Kogan, V.A., Lukov, V.V., and Shcherbakov, I.N., Russ. J. Coord. Chem., 2010, vol. 36, no. 6, p. 401.

    Article  CAS  Google Scholar 

  2. Levchenkov, S.I., Shcherbakov, I.N., Popov, L.D., et al., Izv. Akad. Nauk, Ser. Khim., 2014, vol. 63, no. 3, p. 673.

    CAS  Google Scholar 

  3. Wang, L.-L., Sun, Y.-M., Qi, Z.-N., and Liu, C.-B., J. Phys. Chem. A, 2008, vol. 112, no. 36, p. 8418.

    Article  CAS  Google Scholar 

  4. Vigato, P.A. and Tamburini, S., Coord. Chem. Rev., 2008, vol. 252, nos. 18–20, p. 1871.

    Article  CAS  Google Scholar 

  5. Vigato, P.A., Peruzzo, V., and Tamburini, S., Coord. Chem. Rev., 2012, vol. 256, nos. 11–12, p. 953.

    Article  CAS  Google Scholar 

  6. Kahn, O., Molecular Magnetism, New York: VCH, 1993.

    Google Scholar 

  7. Bleaney, B. and Bowers, K.D., Proc. R. Soc. London. A, 1952, vol. 214, no. 9, p. 451.

    Article  CAS  Google Scholar 

  8. SMART and SAINT. Release 5.0. Area Detector Control and Integration Software, Madison: Bruker AXS, Analytical X-ray Instruments, 1998.

  9. Sheldrick, G.M., SADABS. A Program for Exploiting the Redundancy of Area-Detector X-ray Data, Göttingen: Univ. of Göttingen, 1999.

    Google Scholar 

  10. Sheldrick, G.M., Acta Crystallogr., Sect. A: Found. Crystallogr., 2008, vol. 64, no. 1, p. 112.

    Article  CAS  Google Scholar 

  11. Becke, A.D., J. Chem. Phys., 1993, vol. 98, no. 7, p. 5648.

    Article  CAS  Google Scholar 

  12. Becke, A.D., Phys. Rev. A, 1988, vol. 38, no. 6, p. 3098.

    Article  CAS  Google Scholar 

  13. Lee, C., Yang, W., and Parr, R.G., Phys. Rev. B, 1988, vol. 37, no. 2, p. 785.

    Article  CAS  Google Scholar 

  14. Shcherbakov, I.N., Levchenkov, S.I., Tupolova, Yu.P., et al., Eur. J. Inorg. Chem., 2013, vol. 2013, no. 28, p. 5033.

    CAS  Google Scholar 

  15. Popov, L.D., Shcherbakov, I.N., Levchenkov, S.I., et al., J. Coord. Chem., 2008, vol. 61, no. 3, p. 392.

    Article  CAS  Google Scholar 

  16. Ginsberg, A.P., J. Am. Chem. Soc., 1980, vol. 102, no. 1, p. 111.

    Article  CAS  Google Scholar 

  17. Noodleman, L., Peng, C.Y., Case, D.A., and Mouesca, J.-M., Coord. Chem. Rev., 1995, vol. 144, p. 199.

    Article  CAS  Google Scholar 

  18. Lacroix, P.G. and Daran, J.-C., J. Dalton Trans., 1997, no. 8, p. 1369.

    Google Scholar 

  19. Soda, T., Kitagawa, Y., Onishi, T., et al., Chem. Phys. Lett., 2000, vol. 319, nos. 3–4, p. 223.

    Article  CAS  Google Scholar 

  20. Gaussian 03. Revision D.01, Wallingford: Gaussian Inc., 2004.

  21. Milevskii, B.G., Chibisova, T.A., Solov’eva, N.P., et al., Khim. Geterotsikl. Soed., 2012, vol. 48, no. 12, p. 1903.

    Google Scholar 

  22. Traven’, V.F., Ivanov, I.V., Lebedev, V.S., et al., Izv. Akad. Nauk, Ser. Khim., 2010, vol. 59, no. 8, p. 1565.

    Google Scholar 

  23. Traven, V.F., Ivanov, I.V., Lebedev, V.S., et al., Mendeleev Commun., 2009, vol. 19, no. 4, p. 214.

    Article  CAS  Google Scholar 

  24. Chou, Y.-C., Huang, S.-F., Koner, R., et al., Inorg. Chem., 2004, vol. 43, no. 9, p. 2759.

    Article  CAS  Google Scholar 

  25. Lai, T.-C., Chen, W.-H., Lee, C.-J., et al., J. Mol. Struct., 2009, vol. 935, no. 1, p. 97.

    Article  CAS  Google Scholar 

  26. Popov, L.D., Levchenkov, S.I., Shcherbakov, I.N., et al., Inorg. Chem. Commun., 2012, vol. 17, p. 1.

    Article  CAS  Google Scholar 

  27. Onofrio, N. and Mouesca, J.-M., J. Phys. Chem. A, 2010, vol. 114, no. 20, p. 6149.

    Article  CAS  Google Scholar 

  28. Comba, P., Hausberg, S., and Martin, B., J. Phys. Chem. A, 2009, vol. 113, no. 24, p. 6751.

    Article  CAS  Google Scholar 

  29. Ciofini, I. and Daul, C.A., Coord. Chem. Rev., 2003, vols. 238–239, p. 187.

    Article  Google Scholar 

  30. Illas, F., de P.R. Moreira, I., Bofill, J.M., and Filatov, M., Phys. Rev. B, 2004, vol. 70, no. 13, p. 132414.

    Article  Google Scholar 

  31. Ruiz, E., Cano, J., Alvarez, S., and Alemany, P., J. Comput. Chem., 1999, vol. 20, no. 13, p. 1391.

    Article  CAS  Google Scholar 

  32. Levchenkov, S.I., Shcherbakov, I.N., Popov, L.D., et al., Russ. J. Coord. Chem., 2014, vol. 40, no. 8, p. 523.

    Article  CAS  Google Scholar 

  33. Kou, Y., Tian, J., Li, D., et al., Dalton Trans., 2009, no. 13, p. 2374.

    Google Scholar 

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Authors and Affiliations

  1. Southern Federal University, Rostov-on-Don, 344104, Russia

    I. N. Shcherbakov, L. D. Popov, L. N. Etmetchenko & V. A. Kogan

  2. Southern Scientific Center, Russian Academy of Sciences, Rostov-on-Don, Russia

    S. I. Levchenkov

  3. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Leninskii pr. 31, Moscow, 119991, Russia

    G. G. Aleksandrov

Authors
  1. I. N. Shcherbakov
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  2. S. I. Levchenkov
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  3. L. D. Popov
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  4. G. G. Aleksandrov
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  5. L. N. Etmetchenko
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  6. V. A. Kogan
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Correspondence to I. N. Shcherbakov.

Additional information

Original Russian Text © I.N. Shcherbakov, S.I. Levchenkov, L.D. Popov, G.G. Aleksandrov, L.N. Etmetchenko, V.A. Kogan, 2015, published in Koordinatsionnaya Khimiya, 2015, Vol. 41, No. 2, pp. 67–74.

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Shcherbakov, I.N., Levchenkov, S.I., Popov, L.D. et al. Binuclear copper(II) complex with bis(azomethine) based on 1,3-diaminopropan-2-ol and 4-hydroxy-3-formylcoumarin: Crystal structure and magnetic properties. Russ J Coord Chem 41, 69–75 (2015). https://doi.org/10.1134/S1070328415020098

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  • DOI: https://doi.org/10.1134/S1070328415020098

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