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A new approach to the synthesis of gallium(III) complexes with α-diimine ligands in the radical anion form

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Abstract

A convenient method for the synthesis of gallium(III) complexes with α-diimine ligands DABMe,Mes (N,N′-(butane-2,3-diylidene)bis(2,4,6-trimethylaniline)) or BIANDipp (1,2-bis[(2,6-diisopropylphenyl)imino]acenaphthene) in the radical anion form is found. The method includes the reaction of complexes [Co(DABMe,Mes)Cl2] and [Co(BIANDipp)Cl2] with gallium resulting in the transmetallation and one-electron reduction of the ligand. The synthesized complexes [Ga(DABMe,Mes)Cl2] and [Ga(BIANDipp)Cl2] are characterized by X-ray diffraction analysis and EPR spectroscopy.

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Authors and Affiliations

  1. Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, pr. akademika Lavrent’eva 3, Novosibirsk, 630090, Russia

    P. A. Petrov, S. N. Konchenko & V. A. Nadolinny

  2. Novosibirsk State University, ul. Pirogova 2, Novosibirsk, 630090, Russia

    P. A. Petrov & S. N. Konchenko

Authors
  1. P. A. Petrov
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  2. S. N. Konchenko
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  3. V. A. Nadolinny
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Correspondence to P. A. Petrov.

Additional information

Original Russian Text © P.A. Petrov, S.N. Konchenko, V.A. Nadolinny, 2014, published in Koordinatsionnaya Khimiya, 2014, Vol. 40, No. 12, pp. 717–721.

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Petrov, P.A., Konchenko, S.N. & Nadolinny, V.A. A new approach to the synthesis of gallium(III) complexes with α-diimine ligands in the radical anion form. Russ J Coord Chem 40, 885–890 (2014). https://doi.org/10.1134/S1070328414120100

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  • DOI: https://doi.org/10.1134/S1070328414120100

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