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Synthesis, structure, and mechanism of half-sandwich ruthenium complexes based on ortho-carborane-1,2-dithiolate ligand and alkyne alcohol

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Abstract

A novel complex (p-cymene)Ru(S2C2B10H9)((OH)H2CCCHFc) · 0.5CH2Cl2 (Fc = ferrocenyl) based on the ortho-carborane-1,2-dithiolate ligand and alkyne alcohol has been synthesized successfully and characterized by IR, NMR, MS, elemental analysis and single-crystal X-ray diffraction (CIF file CCDC no. 1007680). The complex crystallizes in monoclinic system, space group C2/c with a = 27.1243(13), b = 11.8161(6), c = 20.8360(11) Å, β = 108.689(3)°, C51H74B20O2S4Cl2Fe2Ru2, Mr = 1448.28, V = 6325.9(6) Å3, ρ c = 1.521 g/cm3, Z = 4, F(000) = 2936, μ(MoK α) = 1.174 mm−1, R = 0.0551 and wR = 0.1518 for 5329 observed reflections (I > 2σ(I)). Structural analysis shows that there are metal-induced B-H activation, the generation of a Ru-B bond, and the coordination of the C=C bond.

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Authors and Affiliations

  1. Key Laboratory of Applied Organic Chemistry, Higher Institutions of Jiangxi Province, School of Chemistry and Chemical Engineering, Shangrao Normal University, Jiangxi, 334001, P.R. China

    J. R. Hu, W. J. Zhang, L. H. Liu & H. N. Peng

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  1. J. R. Hu
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  2. W. J. Zhang
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  3. L. H. Liu
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  4. H. N. Peng
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Correspondence to J. R. Hu.

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Hu, J.R., Zhang, W.J., Liu, L.H. et al. Synthesis, structure, and mechanism of half-sandwich ruthenium complexes based on ortho-carborane-1,2-dithiolate ligand and alkyne alcohol. Russ J Coord Chem 40, 954–958 (2014). https://doi.org/10.1134/S1070328414120057

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  • DOI: https://doi.org/10.1134/S1070328414120057

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