Russian Journal of Coordination Chemistry

, Volume 40, Issue 11, pp 806–812

2-N-Tosylaminobenzaldehyde ferrocenoylhydrazone and its nickel(II) complex: Molecular and crystal structures

  • L. D. Popov
  • E. A. Raspopova
  • A. N. Morozov
  • S. I. Levchenkov
  • G. G. Aleksandrov
  • A. S. Burlov
  • I. N. Shcherbakov
  • V. A. Kogan
Article

DOI: 10.1134/S1070328414110050

Cite this article as:
Popov, L.D., Raspopova, E.A., Morozov, A.N. et al. Russ J Coord Chem (2014) 40: 806. doi:10.1134/S1070328414110050

Abstract

2-N-Tosylaminobenzaldehyde ferrocenoylhydrazone (H2L) and the octahedral nickel(II) complex [Ni(HL)2] · 2CH3OH (I) are synthesized and structurally characterized (CIF files CCDC 981876 (H2L) and 981877 (I)). The crystal structures of both compounds include two independent molecules with different mutual orientations of the tosyl and ferrocene fragments. In a single crystal of H2L, the independent molecules are joined by intermolecular hydrogen bonds into infinite linear chains extended along the crystallographic axis x. The π-stacking interaction between the cyclopentadienyl rings is observed along with hydrogen bonds in a single crystal of complex I.

Copyright information

© Pleiades Publishing, Ltd. 2014

Authors and Affiliations

  • L. D. Popov
    • 1
  • E. A. Raspopova
    • 1
  • A. N. Morozov
    • 1
  • S. I. Levchenkov
    • 2
  • G. G. Aleksandrov
    • 3
  • A. S. Burlov
    • 1
  • I. N. Shcherbakov
    • 1
  • V. A. Kogan
    • 2
  1. 1.Southern Federal UniversityRostov-on-DonRussia
  2. 2.Southern Scientific CenterRussian Academy of SciencesRostov-on-DonRussia
  3. 3.Kurnakov Institute of General and Inorganic ChemistryRussian Academy of SciencesMoscowRussia

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