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Polymeric gold(I) diisobutyl dithiophosphate, [Au2{S2P(O-iso-C4H9)2}2]n: Synthesis, supramolecular self-organization (a role of aurophilic interaction), 13C and 31P MAS NMR spectroscopy, and thermal behavior

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Abstract

A new polymeric gold(I) diisobutyl dithiophosphate (Dtph), [Au2{S2P(O-iso-C4H9)2}2] n (I), was preparatively obtained and characterized by 13C and 31P MAS NMR spectroscopy and X-ray diffraction (CIF file CCDC no. 977818). Diagrams of the χ2 statistic were constructed from the complete 31P MAS NMR spectra and used to calculate the 31P chemical shift anisotropy (δ aniso = δ zz − δ iso ) and the asymmetry parameter η = (δ yy − δ xx )/(δ zz − δ iso ). The main structural unit of complex I is the noncentrosymmetric dinuclear molecule [Au2{S2P(O-iso-C4H9)2}2], in which the gold atoms are linked by two bridging ligands Dtph. The central cyclic structural fragment of the dimer [Au2S4P2] is additionally stabilized by the intramolecular aurophilic interaction Au⋯Au. Further supramolecular self-organization of the complex involves intermolecular aurophilic bonds Au⋯Au that serve to unite adjacent dinuclear molecules [Au2{S2P(O-iso-C4H9)2}2] with different spatial orientations into the polymer chains ([Au2{S2P(O-iso-C4H9)2}2]) n . The thermal behavior of complex I was examined by synchronous thermal analysis under argon. The character of the thermolysis of the complex to reduced metallic gold as a final product was determined.

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References

  1. Lawton, S.L., Rohrbaugh, W.J., and Kokotailo, G.T., Inorg. Chem., 1972, vol. 11, no. 9, p. 2227.

    Article  CAS  Google Scholar 

  2. Lee, Y.-A., McGarrah, J.E., Lachicotte, R.J., and Eisenberg, R., J. Am. Chem. Soc., 2002, vol. 124, no. 36, p. 10662.

    Article  CAS  Google Scholar 

  3. Ivanov, A.V., Lutsenko, I.A., Korneeva, E.V., et al., Rus. J. Coord. Chem., 2012, vol. 38, no. 6, p. 430.

    Article  CAS  Google Scholar 

  4. Ivanov, A.V., Korneeva, E.V., Lutsenko, I.A., et al., J. Mol. Struct., 2013, vol. 1034, p. 152.

    Article  CAS  Google Scholar 

  5. Schmidbaur, H., Gold Bull., 2000, vol. 33, no. 1, p. 3.

    Article  CAS  Google Scholar 

  6. Uson, R., Laguna, A., Laguna, M., et al., Chem. Commun., 1988, no. 11, p. 740.

    Google Scholar 

  7. Pathaneni, S.S. and Desiraju, G.R., Dalton Trans., 1993, no. 2, p. 319.

    Google Scholar 

  8. Cao, L., Jennings, M.C., and Puddephatt, R.J., Inorg. Chem., 2007, vol. 46, no. 4, p. 1361.

    Article  CAS  Google Scholar 

  9. Staples, R.J. and Fackler, Jr., J.P., Inorg. Chem. Commun., 1998, vol. 1, no. 2, p. 51.

    Article  Google Scholar 

  10. Zyl van, W.E., Lopez-de-Luzuriaga, J.M., and Fackler, J.P., Jr., J. Mol. Struct., 2000, vol. 516, no. 1, p. 99.

    Article  Google Scholar 

  11. Zyl van, W.E., Lopez-de-Luzuriaga, J.M., and Mohamed, A.A., et al., Inorg. Chem., 2002, vol. 41, no. 17, p. 4579.

    Article  Google Scholar 

  12. Maspero, A., Kani, I., Mohamed, A.A., et al., Inorg. Chem., 2003, vol. 42, no. 17, p. 5311.

    Article  CAS  Google Scholar 

  13. Karakus, M., Lonnecke, P., Hildebrand, M., and Hey-Hawkins, E., Z. Anorg. Allg. Chem., 2011, vol. 637, nos. 7–8, p. 983.

    Article  CAS  Google Scholar 

  14. Siasios, G. and Tiekink, E.R.T., Z. Kristallogr., 1995, vol. 210, p. 698.

    Article  CAS  Google Scholar 

  15. Preisenberger, M., Bauer, A., Schier, A., and Schmidbaur, H., Dalton Trans., 1997, no. 24, p. 4753.

    Google Scholar 

  16. Gysling, H.J., Blanton, T.N., McMillan, S.M., and Lushington, K.J., Z. Kristallogr., 1999, vol. 214, p. 309.

    Article  CAS  Google Scholar 

  17. Zyl van, W.E., Lopez-de-Luzuriaga, J.M., and Fackler, J.P., Jr., and Staples, R.J., Can. J. Chem., 2001, vol. 79, nos. 5–6, p. 896.

    Google Scholar 

  18. Miller, J.B. and Burmeister, J.L., Synth. React. Inorg. Met.-Org. Chem., 1985, vol. 15, no. 2, p. 223.

    Article  CAS  Google Scholar 

  19. Pines, A., Gibby, M.G., and Waugh, J.S., J. Chem. Phys., 1972, vol. 56, no. 4, p. 1776.

    Article  CAS  Google Scholar 

  20. Press, W.H., Teukolsky, S.A., Vetterling, W.T., and Flannery, B.P., Numerical Recipes, Cambridge: Univ. Press, 1994.

    Google Scholar 

  21. Hodgkinson, P. and Emsley, L., J. Chem. Phys., 1997, vol. 107, no. 13, p. 4808.

    Article  CAS  Google Scholar 

  22. Antzutkin, O.N., Lee, Y.K., and Levitt, M.H., J. Magn. Reson., 1998, vol. 135, no. 1, p. 144.

    Article  CAS  Google Scholar 

  23. Wolfram, S., The Mathematica Book, Cambridge: Wolfram Media/Cambridge Univ., 1999, p. 1470.

    Google Scholar 

  24. APEX2, Madison (WI, USA): Bruker AXS, 2010.

  25. SAINT, Madison (WI, USA): Bruker AXS, 2010.

  26. Sheldrick, G.M., Acta Crystallogr., Sect. A: Found. Crystallogr., 2008, vol. 64, no. 1, p. 112.

    Article  CAS  Google Scholar 

  27. Larsson, A.-C., Ivanov, A.V., Forsling, W., et al., J. Am. Chem. Soc., 2005, vol. 127, no. 7, p. 2218.

    Article  CAS  Google Scholar 

  28. Ivanov, A.V., Antzutkin, O.N., Larsson, A.-C., et al., Inorg. Chim. Acta, 2001, vol. 315, no. 1, p. 26.

    Article  CAS  Google Scholar 

  29. Ivanov, A.V., Loseva, O.V., Ivanov, M.A., et al., Russ. J. Inorg. Chem., 2007, vol. 52, no. 10, p. 1595.

    Article  Google Scholar 

  30. Ivanov, A.V., Gerasimenko, A.V., Antzutkin, O.N., and Forsling, W., Inorg. Chim. Acta, 2005, vol. 358, no. 9, p. 2585.

    Article  CAS  Google Scholar 

  31. Larsson, A.-C., Ivanov, A.V., Antzutkin, O.N., et al., Inorg. Chim. Acta, 2004, vol. 357, no. 9, p. 2510.

    Article  CAS  Google Scholar 

  32. Larsson, A.-C., Ivanov, A.V., Pike, K.J., et al., J. Magn. Reson., 2005, vol. 177, no. 1, p. 56.

    Article  CAS  Google Scholar 

  33. Ivanov, A.V., Zinkin, S.A., Gerasimenko, A.V., et al., Rus. J. Coord. Chem., 2007, vol. 33, no. 1, p. 20.

    Article  CAS  Google Scholar 

  34. Rodina, T.A., Ivanov, A.V., Konfederatov, V.A., et al., Russ. J. Inorg. Chem., 2009, vol. 54, no. 11, p. 1779.

    Article  Google Scholar 

  35. Ivanov, A.V., Konfederatov, V.A., Gerasimenko, A.V., Larsson, A.C., Rus. J. Coord. Chem., 2009, vol. 35, no. 11, p. 857.

    Article  CAS  Google Scholar 

  36. Pauling, L., The Nature of the Chemical Bond and the Structure of Molecules and Crystals, London: Cornell Univ., 1960.

    Google Scholar 

  37. Bondi, A., J. Phys. Chem., 1964, vol. 68, no. 2, p. 441.

    Article  CAS  Google Scholar 

  38. Bondi, A., J. Phys. Chem., 1966, vol. 70, no. 9, p. 3006.

    Article  CAS  Google Scholar 

  39. Evans, D.G. and Boeyens, J.C.A., Acta Crystallogr., Sect. B: Struct. Sci., 1988, vol. 44, no. 6, p. 663.

    Article  Google Scholar 

  40. Lawton, S.L. and Kokotailo, G.T., Inorg. Chem., 1969, vol. 8, no. 11, p. 2410.

    Article  CAS  Google Scholar 

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Authors and Affiliations

  1. Institute of Geology and Nature Management, Far East Branch, Russian Academy of Sciences, Blagoveshchensk, 675000, Russia

    E. V. Korneeva & A. V. Ivanov

  2. Amur State University, Blagoveshchensk, 675027, Russia

    T. A. Rodina

  3. Institute of Chemistry, Far East Branch, Russian Academy of Sciences, pr. Stoletiya Vladivostoka 159, Vladivostok, 690022, Russia

    A. V. Gerasimenko

  4. Luleä University of Technology, S-97187, Luleä, Sweden

    A. -C. Larsson

Authors
  1. E. V. Korneeva
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  2. T. A. Rodina
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  3. A. V. Ivanov
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  4. A. V. Gerasimenko
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  5. A. -C. Larsson
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Correspondence to A. V. Ivanov.

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Original Russian Text © E.V. Korneeva, T.A. Rodina, A.V. Ivanov, A.V. Gerasimenko, A.-C. Larsson, 2014, published in Koordinatsionnaya Khimiya, 2014, Vol. 40, No. 10, pp. 631–640.

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Korneeva, E.V., Rodina, T.A., Ivanov, A.V. et al. Polymeric gold(I) diisobutyl dithiophosphate, [Au2{S2P(O-iso-C4H9)2}2]n: Synthesis, supramolecular self-organization (a role of aurophilic interaction), 13C and 31P MAS NMR spectroscopy, and thermal behavior. Russ J Coord Chem 40, 748–756 (2014). https://doi.org/10.1134/S1070328414100042

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