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Copper(II) and nickel(II) complexes with bis(azomethine)—a condensation product of 1-phenyl-3-methyl-4-formyl-5-mercaptopyrazole with 1,3-diaminopropan-2-ol

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The copper(II) and nickel(II) complexes based on bis(azomethine), which is the condensation product of 1-phenyl-3-methyl-4-formyl-5-mercaptopyrazole with 1,3-diaminopropan-2-ol, are synthesized. Bis-azomethines can form both binuclear and mononuclear complexes in which the hydroxy group is not involved in coordination. The binuclear copper(II) complexes with the acetate and pyrazolate bridges exhibit an antiferromagnetic exchange, which strength is determined by the nature of the bridge (2J = −154 and −424 cm−1, respectively). The structure parameters of the coordination spheres of the complexes are determined by X-ray absorption spectroscopy. The structure of the CHCl3 solvate of the binuclear copper(II) complex with the pyrazolate bridge is solved by X-ray diffraction analysis (CIF file CCDC 964655).

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  1. Casellato, U., Vigato, P.A., and Vidali, M., Coord. Chem. Rev., 1977, vol. 23, no. 1, p. 31.

    Article  CAS  Google Scholar 

  2. Suzuki, M., Furutachi, H., and Okawa, H., Coord. Chem. Rev., 2000, vols. 200–202, no. 1, p. 105.

    Article  Google Scholar 

  3. Vigato, P.A. and Tamburini, S., Coord. Chem. Rev., 2004, vol. 248, nos. 17–20, p. 1717.

    Article  CAS  Google Scholar 

  4. Vigato, P.A., Tamburini, S., and Bertolo, L., Coord. Chem. Rev., 2007, vol. 251, nos. 11–12, p. 1311.

    Article  CAS  Google Scholar 

  5. Kogan, V.A., Lukov, V.V., and Shcherbakov, I.N., Russ. J. Coord. Chem., 2010, vol. 36, no. 6, p. 401.

    Article  CAS  Google Scholar 

  6. Mazurek, W., Kennedy, B.J., Murray, K.S., et al., Inorg. Chem., 1985, vol. 24, no. 20, p. 3258.

    Article  CAS  Google Scholar 

  7. Nishida, Y. and Kida, S., Dalton Trans., 1986, no. 12, p. 2633.

    Google Scholar 

  8. Nishida, Y. and Kida, S., Inorg. Chem., 1988, vol. 27, no. 3, p. 447.

    Article  CAS  Google Scholar 

  9. Fallon, G.D., Markiewicz, A., Murray, K.S., and Quach, T., Chem. Commun., 1991, no. 3, p. 198.

    Google Scholar 

  10. Chou, Y.-C., Huang, S.-F., Koner, R., et al., Inorg. Chem., 2004, vol. 43, no. 9, p. 2759.

    Article  CAS  Google Scholar 

  11. Tupolova, Yu.P., Kogan, V.A., Lukov, V.V., et al., Transition Met. Chem., 2007, vol. 32, no. 5, p. 656.

    Article  CAS  Google Scholar 

  12. Lai, T.-C., Chen, W.-H., Lee, C.-J., et al., J. Mol. Struct., 2009, vol. 935, no. 1, p. 97.

    Article  CAS  Google Scholar 

  13. Kou, Y., Tian, J., Li, D., et al., Dalton Trans., 2009, no. 13, p. 2374.

    Google Scholar 

  14. Popov, L.D., Tupolova, Yu.P., Lukov, V.V., et al., Inorg. Chim. Acta, 2009, vol. 362, no. 6, p. 1673.

    Article  CAS  Google Scholar 

  15. Popov, L.D., Levchenkov, S.I., Shcherbakov, I.N., et al., Inorg. Chem. Commun., 2012, vol. 17, p. 1.

    Article  CAS  Google Scholar 

  16. Kvitko, I.Ya. and Porai-Koshits, B.A., Zh. Org. Khim., 1969, vol. 5, no. 9, p. 1685.

    CAS  Google Scholar 

  17. SMART and SAINT. Release 5.0. Area Detector Control and Integration Software, Madison (WI, USA): Bruker AXS, 1998.

  18. Sheldrick, G.M., SADABS. A Program for Exploiting the Redundancy of Area-Detector X-ray Data, Göttingen (Germany): Univ. of Göttingen, 1999.

    Google Scholar 

  19. Sheldrick, G.M., Acta Crystallogr., Sect. A: Found. Crystallogr., 2008, vol. 64, no. 1, p. 112.

    Article  CAS  Google Scholar 

  20. Kochubei, D.I., Babanov, Yu.A., Zamaraev, K.I., et al., Rentgenospektral’nyi metod izucheniya struktury amorfnykh tel: EXAFS-spektroskopiya (X-ray Spectral Method for Investigation of the Structures of Amorphous Solids: EXAFS Spectroscopy), Novosibirsk: Nauka Sib. otd., 1988.

    Google Scholar 

  21. Newville, M., J. Synchrotron Rad., 2001, no. 8, p. 96.

    Google Scholar 

  22. Zabinski, S.I., Rehr, J.J., Ankudinov, A., and Alber, R.C., Phys. Rev., vol. 52, p. 2995.

  23. Hennig, L., Kirmse, R., Hammerich, O., et al., Inorg. Chim. Acta, 1995, vol. 234, nos. 1–2, p. 67.

    Article  CAS  Google Scholar 

  24. Rasmussen, J.C., Toftlund, H., Nivorzhkin, A.N., et al., Inorg. Chim. Acta, 1996, vol. 251, nos. 1–2, p. 291.

    Article  CAS  Google Scholar 

  25. Uraev, A.I., Vasil’chenko, I.S., Borodkin, G.S., et al., Izv. Akad. Nauk, Ser. Khim., 2005, vol. 54, no. 3, p. 623.

    Google Scholar 

  26. Kukushkin, Yu.N., Khodzhaev, O.F., Budanova, V.F., and Parpiev, N.A., Termoliz koordinatsionnykh soedinenii (Thermolysis of Coordination Compounds), Tashkent: Fan, 1986.

    Google Scholar 

  27. Kahn, O., Molecular Magnetism, New York: VCH Publishers, 1993.

    Google Scholar 

  28. Bleaney, B. and Bowers, K.D., Proc. R. Soc. London. A, 1952, vol. 214, no. 1119, p. 451.

    Article  CAS  Google Scholar 

  29. Yamamoto, T., X-ray Spectrom., 2008, vol. 37, no. 6, p. 572.

    Article  CAS  Google Scholar 

  30. Nagatani, H., Tanida, H., Watanabe, I., and Sagara, T., Anal. Sci., 2009, vol. 25, no. 4, p. 475.

    Article  CAS  Google Scholar 

  31. Chen, L.X., Shaw, G.B., Liu, T., et al., Chem. Phys., 2004, vol. 299, nos. 2–3, p. 215.

    Article  CAS  Google Scholar 

  32. Choy, J.-H., Yoon, J.-B., and Jung, H., J. Phys. Chem. B, 2002, vol. 106, no. 43, p. 11120.

    Article  CAS  Google Scholar 

  33. Popov, L.D., Levchenkov, S.I., Shcherbakov, I.N., et al., Russ. J. Coord. Chem., 2013, vol. 39, no. 10, p. 689.

    Article  CAS  Google Scholar 

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Correspondence to S. I. Levchenkov.

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Original Russian Text © A.I. Uraev, L.D. Popov, S.I. Levchenkov, I.N. Shcherbakov, V.G. Vlasenko, K.Yu. Suponitskii, S.S. Beloborodov, D.A. Garnovskii, V.A. Kogan, 2014, published in Koordinatsionnaya Khimiya, 2014, Vol. 40, No. 9, pp. 515–522.

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Uraev, A.I., Popov, L.D., Levchenkov, S.I. et al. Copper(II) and nickel(II) complexes with bis(azomethine)—a condensation product of 1-phenyl-3-methyl-4-formyl-5-mercaptopyrazole with 1,3-diaminopropan-2-ol. Russ J Coord Chem 40, 599–606 (2014).

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