Abstract
Two Mn(II) sulfoterephthalate complexes, [Mn(HStp)(o-Phen)2] (I) and [Mn(HStp)(2,2′-Bipy)2] (II) (H3Stp = 2-sulfoterephthalic acid, o-Phen = 1,10-phenanthroline, 2,2′-Bipy = 2,2′-bipyridine), were synthesized under hydrothermal condition. Single crystal X-ray diffraction analyses reveal that complexes I and II possess similar structure, in which the center Mn2+ ions are hexa-coordinated with one Hstpanion and two N-donor ligands. For both of them, the formation of 3D supramolecular structures are based on both H-bonds and π...π/C-H...π stacking interactions. Electrochemical properties of complexes I and II have been investigated by means of cyclic voltmetry, which shows that electron transfer between Mn(III) and Mn(II) in electrolysis is quasi-reversible process.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
References
Weng, D.F., Wang, Z.M., and Gao, S., Chem. Soc. Rev., 2011, vol. 40, p. 3157.
Xie, Z.G., Wang, C., de Krafft, K.E., and Lin, W.B., J. Am. Chem. Soc., 2011, vol. 133, p. 2056.
Cheethan, A.K. and Rao, C.N.R., Science, 2007, vol. 318, p. 58.
Zhang, M.B., Chen, H.M., Hu, R.X., and Chen, Z.L., CrystEngComm, 2011, vol. 13, p. 7019.
Liu, D., Ren, Z.G., Li, H.X., et al., CrystEngComm, 2010, vol. 12, p. 1912.
Zheng, S.T., Wu, T., Zhang, J., et al., Angew. Chem. Int. Ed., 2010, vol. 49, p. 5362.
Chen, M.S., Tan, X.W., Zhang, C.H., and Kuang, D.Z., Z. Anorg. Allg. Chem., 2011, vol. 637, p. 1220.
Zhang, M.L., Xing, F.G., and Wang, Z.L., Chin. J. Struct. Chem., 2010, vol. 29, p. 592.
Ren, P., Shi, W., and Cheng, P., Cryst. Growth Des., 2008, vol. 8, p. 1097.
Taguchi, T., Wernsdorfe, W., Abboud, K.A., and Christou, G., Inorg. Chem., 2010, vol. 49, p. 10579.
Meng, M., Zhong, D.C., and Lu, T.B., CrystEngComm, 2011, vol. 13, p. 6794.
Xiao, H.P., Zheng, Y.X., Liang, X.Q., et al., J. Mol. Struct., 2008, vol. 888, p. 55.
Horike S., Matsuda R., Tanaka D., et al., Angew. Chem. Int. Ed., 2006, vol. 45, p. 7226.
Lian, Z.X., Zhang, J.M., Xu, M.L., et al., Acta Crystallogr. C, 2007, vol. 63, p. m445.
Horike, S., Matsuda, R., Tanaka, D., et al., J. Am. Chem. Soc., 2006, vol. 128, p. 4222.
Horike, S., Bureekaew, S., and Kitagawa, S., Chem. Commun., 2008, p. 471.
Siemens, SAINT, Area Detector Control and Iintegration Software, Madison (WI, USA): Siemens Analytical X-ray Instruments Inc., 1996.
Sheldrick, G.M., SHELX-97 and SHELXTL, Software Reference Manual, Version 5.1, Madison (WI, USA): Brucker AXS Inc., 1997.
Sheldrick, G.M., SADABS, Program for Empirical Absorption Correction of Area Detector Data, Göttingen (Germany): Univ. of Göttingen, 1996.
Wen, L.L., Wang, F., Feng, J., et al., Cryst. Growth Des., 2009, vol. 9, p. 3581.
Forbes T.Z. and Sevov S.C., Inorg. Chem., 2009, vol. 48, p. 6873.
Liu C.M., Zhang D.Q., and Zhu, D.B., Inorg. Chem., 2009, vol. 48, p. 792.
Wang, J., Zheng, S.L., Hu, S., et al., Inorg. Chem., 2007, vol. 46, p. 795.
Fan, R.Q., Wang, P., Ren, J.Y., et al., Spectroscopy and Spectral Analysis, 2011, vol. 31, p. 1734.
Ding, Y., Xia, C.F., Hu, Z.Q., et al., Acta Chim. Sinica, 2009, vol. 14, p. 1579.
Lv, Y.K., Feng, Y.L., Liu, J.W., et al., Chin. J. Inorg. Chem., 2011, vol. 27, p. 791.
Yan, S.H., Jiang, D.M., Zhang, Y., et al., Chin. J. Inorg. Chem., 2011, vol. 27, p. 1191.
Author information
Authors and Affiliations
Corresponding author
Additional information
The article is published in the original.
Rights and permissions
About this article
Cite this article
Ren, Y., Hao, T., Zhang, M. et al. Crystal structures and electrochemical properties of two Mn(II) 2-sulfoterephthalate complexes with N-donor ligands. Russ J Coord Chem 40, 154–159 (2014). https://doi.org/10.1134/S1070328414030075
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S1070328414030075