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Cluster complexes [Mo3O2S2(Acac)3(Amine)3]PF6

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Abstract

New mixed-ligand cluster complexes [Mo3O2S2(Acac)3(Amine)3]PF6 (Amine = morpholine (Mor), 4-cyanopyridine (PyCN), pyrazine (Pz)) have been synthesized. The compounds were characterized by IR spectroscopy and mass spectrometry (ESI-MS). The crystal structure of the Mor complex, which was isolated as [Mo3(μ3-S)(μ2-O)2(μ2-S)(Acac)3(Mor)3]PF6 · 0.5Mor · 0.3(CH3)2CO was determined. The stability of the complexes in methanolic solutions decreases in a row: Mor > PyCN > Pz.

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Authors and Affiliations

  1. Nikolaev Institute of Inorganic Chemistry Siberian Branch of Russian Academy of Science, Novosibirsk, Russia

    P. A. Abramov, J. A. Laricheva, E. V. Peresypkina & M. N. Sokolov

  2. Novosibirsk State University, Novosibirsk, Russia

    P. A. Abramov & M. N. Sokolov

Authors
  1. P. A. Abramov
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  2. J. A. Laricheva
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  3. E. V. Peresypkina
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  4. M. N. Sokolov
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Correspondence to P. A. Abramov.

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Original Russian Text © P.A. Abramov, J.A. Laricheva, E.V. Peresypkina, M.N. Sokolov, 2014, published in Koordinatsionnaya Khimiya, 2014, Vol. 40, No. 3, pp. 171–178.

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Abramov, P.A., Laricheva, J.A., Peresypkina, E.V. et al. Cluster complexes [Mo3O2S2(Acac)3(Amine)3]PF6 . Russ J Coord Chem 40, 171–178 (2014). https://doi.org/10.1134/S1070328414030014

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  • DOI: https://doi.org/10.1134/S1070328414030014

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