Skip to main content
SpringerLink
Log in

Synthesis, crystal structures, and properties of inorganic-organic hybrid complexes constructed from copper(II) macrocyclic fragment

  • Published:
Russian Journal of Coordination Chemistry Aims and scope Submit manuscript

Abstract

Reaction of a macrocyclic copper(II) complex [Cu(L)](ClO4)2 · 3H2O (I) (L = 1,3,10,12,16,19-hexaazatetracyclotetracosane) with a hexapod carboxylate ligand H6TTHA (H6TTHA = 1,3,5-triazine-2,4,6-triamine hexaacetic acid) and a tripod carboxylate ligand H3TATB (H3TATB = 4,4′,4″-S-triazine-2,4,6-triyl-tribenzoic acid) yielded two mononuclear copper(II) complexes [Cu(L)][H4TTHA] · 4H2O (II) and [Cu(L)][HTATB] · 4H2O (III). The complexes I–III have been structurally characterized. The crystal structures of complexes II and III show the copper(II) ion has a distorted pentacoordinate square-pyramidal geometry with two secondary and two tertiary amines from the macrocyclic complex [Cu(L)]2+ and one oxygen atom from the carboxylate ligand group at the axial position. The UV-Vis spectra are utilized to discuss the hydrolysis of the complex II.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Suh, M.P., Cheon, Y.E., and Lee, E.Y., Coord. Chem. Rev., 2008, vol. 252, p. 1007.

    Article  CAS  Google Scholar 

  2. Park, H.J. and Suh, M.P., Chem. Commun., 2010, p. 610.

    Google Scholar 

  3. Choi, H.S. and Suh, M.P., Angew. Chem. Int. Ed., 2009, vol. 48, p. 6865.

    Article  CAS  Google Scholar 

  4. Moon, H.R., Kim, J.H., and Suh, M.P., Angew. Chem., Int. Ed., 2005, vol. 44, p. 1261.

    Article  CAS  Google Scholar 

  5. Lee, E.Y. and Suh, M.P., Angew. Chem. Int. Ed., 2004, vol. 43, p. 2798.

    Article  CAS  Google Scholar 

  6. Choi, H.J. and Suh, M.P., J. Am. Chem. Soc., 2004, vol. 126, p. 15844.

    Article  CAS  Google Scholar 

  7. Cheon, Y.E. and Suh, M.P., Chem. Eur. J., 2008, vol. 14, p. 3961.

    Article  CAS  Google Scholar 

  8. Suh, M.P., Moon, H.R., Lee, E.Y., and Jang, S.Y., J. Am. Chem. Soc., 2006, vol. 128, p. 4710.

    Article  CAS  Google Scholar 

  9. Suh, M.P. and Cheon, Y.E., Aust. J. Chem., 2006, vol. 59, p. 605.

    Article  CAS  Google Scholar 

  10. Lu, T.B., Ou, G.C., Jiang, L., et al., Inorg. Chim. Acta, 2005, vol. 358, p. 3241.

    Article  CAS  Google Scholar 

  11. Lu, T.B., Xiang, H., Luck, R.L., et al., New J. Chem., 2002, vol. 26, p. 969.

    Article  CAS  Google Scholar 

  12. Lu, T.B., Xiang, H., Su, C.Y., et al., New J. Chem., 2001, vol. 25, p. 216.

    Article  Google Scholar 

  13. Ni, Z.-H., Kou, H.-Z., Zhao, H.-Y., et al., Inorg. Chem., 2005, vol. 44, p. 2050.

    Article  CAS  Google Scholar 

  14. Zhang, B., Ni, Z.-H., Cui, A.-L., and Kou, H.-Z., New J. Chem., 2006, vol. 30, p. 1327.

    Article  CAS  Google Scholar 

  15. Kou, H.-Z., Gao, S., Ma, B.-Q., and Liao, D.-Z., Chem. Commun., 2000, p. 1309.

    Google Scholar 

  16. Kim, H. and Suh, M.P., Inorg. Chem., 2005, vol. 44, p. 810.

    Article  CAS  Google Scholar 

  17. Choi, H.J. and Suh, M.P., Eur. J. Inorg. Chem., 2010, vol. 24, p. 3795.

    Google Scholar 

  18. Wang, Y., Cao, R., Bi, W., et al., J. Mol. Struct., 2005, vol. 738, p. 51.

    Article  CAS  Google Scholar 

  19. Tao, B., Jiang, X., Li, X., et al., J. Mol. Struct., 2011, vol. 1003, p. 111.

    Article  CAS  Google Scholar 

  20. Park, H.J. and Suh, M.P., CrystEngComm, 2012, vol. 14, p. 2748.

    Article  CAS  Google Scholar 

  21. Choi, K.Y., J. Coord. Chem., 2003, vol. 56, p. 481.

    Article  CAS  Google Scholar 

  22. Choi, K.Y., Kim, M.H., and Kim, M.J., Transition Met. Chem., 2004, vol. 29, p. 904.

    Article  CAS  Google Scholar 

  23. Choi, K.Y., J. Mol. Evol., 2010, vol. 20, p. 867.

    CAS  Google Scholar 

  24. Jiang, X., Tao, B., Xia, H., and Liao, G.Y., CrystEng-Comm, 2012, vol. 14, p. 3271.

    Article  CAS  Google Scholar 

  25. Sheldrick, G.M., SHELXS-97, Program for Solution of Crystal Structures, Göttingen (Germany): Univ. of Göttingen, 1997.

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Faculty of Material Science and Chemistry, China University of Geosciences, Wuhan, 430074, P.R. China

    H. Xia, X. Jiang, C. Jiang & G. Liao

  2. State Key Laboratory of Geological Processes and Mineral Resources, China University of Geosciences, Wuhan, 430074, P.R. China

    L. Lin

Authors
  1. H. Xia
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. X. Jiang
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. L. Lin
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. C. Jiang
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. G. Liao
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding authors

Correspondence to H. Xia or G. Liao.

Additional information

The article is published in the original.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Xia, H., Jiang, X., Lin, L. et al. Synthesis, crystal structures, and properties of inorganic-organic hybrid complexes constructed from copper(II) macrocyclic fragment. Russ J Coord Chem 39, 896–901 (2013). https://doi.org/10.1134/S1070328413120099

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S1070328413120099

Keywords

Search

Navigation