Russian Journal of Coordination Chemistry

, Volume 39, Issue 12, pp 813–821 | Cite as

Direct electrochemical and chemical syntheses, structures, and properties of metal complexes of azo compounds with an additional azo group in the amine fragment

  • A. S. Burlov
  • S. A. Mashchenko
  • A. S. Antsyshkina
  • G. G. Sadikov
  • V. S. Sergienko
  • M. A. Kiskin
  • S. A. Nikolaevskii
  • V. G. Vlasenko
  • Ya. V. Zubavichus
  • A. I. Uraev
  • D. A. Garnovskii
  • E. V. Korshunova
  • S. I. Levchenkov
Article

Abstract

New complexes of Cu(II), Co(II), and Ni(II) with 1-phenyl-3-methyl-4-[(4-phenylazophenyl)hydrazono]-5H-pyrazol-5-one and 1-phenyl-3-methyl-4-[4-methyl-2-(4-methylphenylazophenyl)hydrazono]-5H-pyrazol-5-one are synthesized by the chemical and electrochemical methods and characterized by IR, 1H NMR, and EXAFS spectroscopy and X-ray diffraction analysis. Depending on the complexing metal and position of the additional azo group, the latter is involved or not in coordination with the metal to form heterounit five- and six-membered metallocycles.

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Copyright information

© Pleiades Publishing, Ltd. 2013

Authors and Affiliations

  • A. S. Burlov
    • 1
  • S. A. Mashchenko
    • 1
  • A. S. Antsyshkina
    • 2
  • G. G. Sadikov
    • 2
  • V. S. Sergienko
    • 2
  • M. A. Kiskin
    • 2
  • S. A. Nikolaevskii
    • 1
  • V. G. Vlasenko
    • 3
  • Ya. V. Zubavichus
    • 4
  • A. I. Uraev
    • 1
  • D. A. Garnovskii
    • 5
  • E. V. Korshunova
    • 1
  • S. I. Levchenkov
    • 5
  1. 1.Research Institute of Physical and Organic ChemistrySouthern Federal UniversityRostov-on-DonRussia
  2. 2.Kurnakov Institute of General and Inorganic ChemistryRussian Academy of SciencesMoscowRussia
  3. 3.Research Institute of PhysicsSouthern Federal UniversityRostov-on-DonRussia
  4. 4.Kurchatov Institute Russian Research CenterMoscowRussia
  5. 5.Southern Scientific CenterRussian Academy of SciencesRostov-on-DonRussia

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