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Syntheses, structural characterization, and antibacterial properties of a hexanuclear bimetallic cluster complex

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Abstract

A new bimetallic cluster complex with the formular {[Cu(Phen)2]2V4O12} · MeOH · 5H2O has been synthesized and structurally characterized by elemental analyses, IR spectrum, and single crystal X-ray diffraction. The heterobimetallic cluster complex is composed of a discrete V4O 4−12 cluster covalently attached to two [Cu(Phen)2] 2+2 fragments. The nonclassical hydrogen bonds and π-π stacking contribute to the formation of the three-dimensional supramolecular structure. Microdilution broth method indicated that the complex showed significant activity against B. subtilis, S. aureus, and E. coli.

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Authors and Affiliations

  1. College of Chemistry and Materials Engineering, GuiYang University, Guiyang, 550005, P.R. China

    G. L. Zhang, L. Ran, R. G. Hu & J. Zeng

  2. GuiZhou Provincial High College Key and Special Laboratory for Pest Management and Resource, GuiYang University, Guiyang, 550005, P.R. China

    G. L. Zhang

  3. Institute of Resources Environment and Disaster, Guizhou normal College, Guiyang, 550018, P.R. China

    X. Q. Luo

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  1. G. L. Zhang
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  2. L. Ran
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  3. X. Q. Luo
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  4. R. G. Hu
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  5. J. Zeng
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Correspondence to G. L. Zhang.

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Zhang, G.L., Ran, L., Luo, X.Q. et al. Syntheses, structural characterization, and antibacterial properties of a hexanuclear bimetallic cluster complex. Russ J Coord Chem 39, 792–797 (2013). https://doi.org/10.1134/S1070328413100138

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  • DOI: https://doi.org/10.1134/S1070328413100138

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