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Synthesis and crystal structures of dimeric schiff base oxovanadium(V) complexes with antimicrobial activity

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Abstract

Two new dimeric oxovanadium(V) complexes, [VO2L1]2 · 2H2O (I) and [VO2L2]2 (II), where L1 and L2 are the monoanionic form of 5-methoxy-2-[(2-methylaminoethylimino)methyl]phenol (HL1) and 5-diethylamino-2-[(2-methylaminoethylimino)methyl]phenol (HL2), respectively, have been synthesized and characterized by elemental analysis, FT-IR spectra, and single crystal X-ray determination. The crystal of I is monoclinic: space group P21, a = 6.858(2), b = 16.630(3), c = 12.306(2) Å, β = 103.985(2)°, V = 1361.9(5) Å3, Z = 2. The crystal of II is triclinic: space group \(P\bar 1\), a = 7.378(2), b = 8.838(2), c = 13.312(3) Å, α = 102.576(2)°, β = 92.044(2)°, γ = 113.017(2)°, V = 772.7(3) Å3, Z = 2. The V...V distances are 3.140(1) Å in I and 3.254(1) Å in II. The V atoms in the complexes are in octahedral coordination. The effect of the complexes on the antimicrobial activity against Staphylococcus aureus, Escherichia coli, and Candida albicans was studied.

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References

  1. Li, X., Lah, M.S., and Pecoraro, V.L., Inorg. Chem., 1988, vol. 27, no. 25, p. 4657.

    Article  CAS  Google Scholar 

  2. Monga, V., Thompson, K.H., Yuen, V.G., et al., Inorg. Chem., 2005, vol. 44, no. 8, p. 2678.

    Article  CAS  Google Scholar 

  3. del Rio, D., Galindo, A., Tejedo, J., et al., Inorg. Chem. Commun., 2000, vol. 3, no. 1, p. 32.

    Article  Google Scholar 

  4. Grüning, C., Schmidt, H., and Rehder, D., Inorg. Chem. Commun., 1999, vol. 2, no. 1, p. 57.

    Article  Google Scholar 

  5. Sonmez, M., Celebi, M., and Berber, I., Eur. J. Med. Chem., 2010, vol. 45, no. 5, p. 1935.

    Article  Google Scholar 

  6. Mohamed, G.G., Omar, M.M., and Ibrahim, A.A., Eur. J. Med. Chem., 2009, vol. 44, no. 12, p. 4801.

    Article  CAS  Google Scholar 

  7. Sinha, D., Tiwari, A.K., Singh, S., et al., Eur. J. Med. Chem., 2008, vol. 43, no. 1, p. 160.

    Article  CAS  Google Scholar 

  8. Bagihalli, G.B., Avaji, P.G., Patil, S.A., et al., Eur. J. Med. Chem., 2008, vol. 43, no. 12, p. 2639.

    Article  CAS  Google Scholar 

  9. Sun, Y.-X., Synth. React. Inorg. Met.-Org. Nano-Met. Chem., 2006, vol. 36, no. 8, p. 621.

    Article  CAS  Google Scholar 

  10. SMART and SAINT, Area Detector Control and Integration Software, Madison (WI, USA): Bruker Analytical X-ray Instruments Inc., 1997.

  11. Sheldrick, G.M., SADABS, Program for Empirical Absorption Correction of Area Detector Data, Göttingen (Germany): Univ. of Göttingen, 1997

    Google Scholar 

  12. North, A.C.T., Phillips, D.C., and Mathews, F.S., Acta Crystallogr., A, 1968, vol. 24, no. 3, p. 351.

    Article  Google Scholar 

  13. Sheldrick, G.M., SHELXL-97, Program for the Refinement of Crystal Structures, Göttingen (Germany): Univ. of Göttingen, 1997

    Google Scholar 

  14. Duncan, C.A., Copeland, E.P., Kahwa, I.A., et al., Dalton Trans., 1997, no. 6, p. 917.

    Google Scholar 

  15. Mokry, L.M. and Carrano, C.J., Inorg. Chem., 1993, vol. 32, no. 26, p. 6119.

    Article  CAS  Google Scholar 

  16. Mondal, S., Mukherjee, M., Dhara, K., et al., Cryst. Growth Des., 2007, vol. 7, no. 9, p. 1716.

    Article  CAS  Google Scholar 

  17. Abe, Y., Lyoda, A., Seto, K., et al., Eur. J. Inorg. Chem., 2008, no. 13, p. 2148.

    Google Scholar 

  18. Barry, A., in Antibiotics in Laboratory Medicine, Lorian, V., Ed., Baltimore: Williams and Wilkins, 1991, p. 1.

  19. Rosu, T., Negoiu, M., Pasculescu, S., et al., Eur. J. Med. Chem., 2010, vol. 45, no. 2, p. 774.

    Article  CAS  Google Scholar 

  20. Searl, J.W., Smith, R.C., and Wyard, S., J. Proc. Phys. Soc., 1961, vol. 78, no. 505, p. 1174.

    Article  CAS  Google Scholar 

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Authors and Affiliations

  1. College of Chemistry and Chemical Engineering, Pingdingshan University, Pingdingshan, Henan, 467000, P.R. China

    G. X. He, L. W. Xue & G. Q. Zhao

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  1. G. X. He
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  2. L. W. Xue
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  3. G. Q. Zhao
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Correspondence to L. W. Xue.

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He, G.X., Xue, L.W. & Zhao, G.Q. Synthesis and crystal structures of dimeric schiff base oxovanadium(V) complexes with antimicrobial activity. Russ J Coord Chem 39, 710–715 (2013). https://doi.org/10.1134/S1070328413100023

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  • DOI: https://doi.org/10.1134/S1070328413100023

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