Russian Journal of Coordination Chemistry

, Volume 39, Issue 7, pp 493–499 | Cite as

Crystal structure and magnetic properties of the binuclear copper(II) complex with 2,6-diformyl-4-tert-butylphenol bis(imidazolinylhydrazone)

  • S. I. Levchenkov
  • L. D. Popov
  • I. N. Shcherbakov
  • G. G. Aleksandrov
  • A. A. Tsaturyan
  • S. S. Beloborodov
  • O. V. Maevskii
  • V. A. Kogan
Article

Abstract

The binuclear copper(II) complex with 2,6-diformyl-4-tert-butylphenol bis(imidazolinylhydrazone) (H3L), [Cu2(H2L)Br2]ClO4 (I), was synthesized. The structure of complex I was determined by X-ray diffraction analysis. The antiferromagnetic exchange interaction (2J = −108 cm−1) translated through the phenoxide oxygen atom is observed between the copper(II) ions. The exchange parameter was calculated by the quantum-chemical “broken symmetry” method.

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Copyright information

© Pleiades Publishing, Ltd. 2013

Authors and Affiliations

  • S. I. Levchenkov
    • 1
  • L. D. Popov
    • 2
  • I. N. Shcherbakov
    • 2
  • G. G. Aleksandrov
    • 3
  • A. A. Tsaturyan
    • 2
  • S. S. Beloborodov
    • 2
  • O. V. Maevskii
    • 2
  • V. A. Kogan
    • 2
  1. 1.Southern Scientific CenterRussian Academy of SciencesRostov-on-DonRussia
  2. 2.Southern Federal UniversityRostov-on-DonRussia
  3. 3.Kurnakov Institute of General and Inorganic ChemistryRussian Academy of SciencesMoscowRussia

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