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A new layered lead(II) MOF with helical chain motif: synthesis, crystal structure, and fluorescence

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Abstract

A novel layered MOF, {[Pb2(H2Bic)(HBic)Cl3] · 2H2O} n (I), was hydrothermally obtained by the reaction of PbCl2 with 1-H-benzimidazole-5-carboxylic acid (H2Bic) and fully characterized by single-crystal X-ray diffraction, elemental analysis, FT-IR, TG-DTA, and luminescent spectra. Structural analysis suggests that complex I is a 2D layer assembled from helical Pb(II)-HBicchains and bridging chloride linkers, which is H-bonded together into a 3D supramolecular network. Additionally, I in the solid-state exhibits a favorable fluorescent emission at room temperature due to the intraligand charge transfer, suggesting its potential application as fluorescence materials.

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References

  1. Chakrabarty, R., Mukherjee, P.S., and Stang, P.J., Chem. Rev., 2011, vol. 111, p. 6810.

    Article  CAS  Google Scholar 

  2. Forgan, R.S., Sauvage, J.-P., and Stoddart, J.F., Chem. Rev., 2011, vol. 111, p. 5434.

    Article  CAS  Google Scholar 

  3. Yang, E.-C., Liu, Z.-Y., Wu X.-Y., and Zhao, X.-J., Chem. Commun., 2011, vol. 47, p. 8629.

    Article  CAS  Google Scholar 

  4. Yam, V.W.W. and Lo, K.K.W., Chem. Soc. Rev., 1999, vol. 28, p. 323.

    Article  CAS  Google Scholar 

  5. Yoon, M., Chem. Rev., 2012, vol. 112, p. 1196.

    Article  CAS  Google Scholar 

  6. Kitagawa, J., Kitaura, R., and Noro, S., Angew. Chem., Int. Ed., 2004, vol. 43, p. 2334.

    Article  CAS  Google Scholar 

  7. Nowicka, B., Rams, M., Stadnicka, K., and Sieklucka, B., Inorg. Chem., 2007, vol. 46, p. 8123.

    Article  CAS  Google Scholar 

  8. Yang, E.-C., Liu, Z.-Y., Wang, X.-G., et al., CrystEng-Comm, 2008, vol. 10, p. 1140.

    Article  CAS  Google Scholar 

  9. Yang, E.-C., Liu, Z.-Y., Shi, X.-J., et al., Inorg. Chem., 2010, vol. 49, 7969.

    Article  CAS  Google Scholar 

  10. Yang, E.-C., Liu, T.-Y., Wang, Q., and Zhao, X.-J., Inorg. Chem. Commun., 2011, vol. 14, p. 285.

    Article  CAS  Google Scholar 

  11. Guo, Z.-G., Yuan, D.-Q., Bi, W.-H., et al., J. Mol. Struct., 2006, vol. 782, p. 106.

    Article  CAS  Google Scholar 

  12. Liu, Z., Chen, Y., Liu, P., et al., J. Solid State Chem., 2005, vol. 178, p. 2306.

    Article  CAS  Google Scholar 

  13. Zhao, L.-N., Liu, T.-Y., Liu, Z.-Y., et al., Z. Anorg. Allg. Chem., 2010, vol. 636, p. 2709.

    Article  CAS  Google Scholar 

  14. Yao, Y.-L., Che, Y.-X., and Zheng, J.-M., Inorg. Chem. Commun., 2008, vol. 11, p. 883.

    Article  CAS  Google Scholar 

  15. Guo, Z.-G., Li, X.-J., Gao, S.-Y., et al., J. Mol. Struct., 2007, vol. 846, p. 123.

    Article  CAS  Google Scholar 

  16. Guo, Z.-G., Cao, R., Li, X.-J., et al., Eur. J. Inorg. Chem., 2007, p. 742.

    Google Scholar 

  17. Parr, J., Polyhedron, 1997, vol. 16, p. 551.

    Article  CAS  Google Scholar 

  18. SAINT, Software Reference Manual, Madison (WI, USA): Bruker AXS, 1998.

  19. Sheldrick, G.M., SADABS, Program for Empirical Absorption Correction of Area Detector Data, Göttingen (Germany): Univ. of Göttingen, 1996.

    Google Scholar 

  20. Sheldrick, G.M., SHELXTL, Structure Determination Software Programs, Madison (WI, USA): Bruker Analytical X-Ray System, Inc., 2001.

    Google Scholar 

  21. Yang, E.-C., Li, J., Ding, B., et al., CrystEngComm, 2008, vol. 10, p. 158.

    Article  CAS  Google Scholar 

  22. Durkin, J.J., Francis, M.D., Hitchcock, P.B., et al., Dalton Trans., 1999, p. 4057.

    Google Scholar 

  23. Soudi, A.A., Morsali, A., and Moazzenchi, S., Inorg. Chem. Commun., 2006, vol. 9, p. 1259.

    Article  CAS  Google Scholar 

  24. Casas, J.S., Castellano, E.E., Ellena, J., et al., Inorg. Chem., 2003, vol. 42, p. 2584.

    Article  CAS  Google Scholar 

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Authors and Affiliations

  1. College of Chemistry, Tianjin Key Laboratory of Structure and Performance for Functional Molecules, Tianjin Normal University, Tianjin, 300387, P.R. China

    X. G. Wang, E. C. Wang & E. C. Yang

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  1. X. G. Wang
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  2. E. C. Wang
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  3. E. C. Yang
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Correspondence to E. C. Yang.

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Wang, X.G., Wang, E.C. & Yang, E.C. A new layered lead(II) MOF with helical chain motif: synthesis, crystal structure, and fluorescence. Russ J Coord Chem 39, 524–528 (2013). https://doi.org/10.1134/S1070328413060110

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  • DOI: https://doi.org/10.1134/S1070328413060110

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