Russian Journal of Coordination Chemistry

, Volume 39, Issue 4, pp 342–346

Tetranuclear Copper(II) Complex with N,N′-bis(2-N-Tosylaminobenzylidene)-1,3-Diaminopropan-2-ol: Crystal structure and magnetic properties

  • L. D. Popov
  • S. I. Levchenkov
  • I. N. Shcherbakov
  • K. Yu. Suponitskii
  • A. S. Burlov
  • S. S. Beloborodov
  • V. V. Lukov
  • V. A. Kogan
Article

Abstract

Tetranuclear copper(II) complex, [Cu4L2(OOCCH2COO)], where L is triply deprotonated bis-N,N′-(2-N-tosylaminobenzylidene)-1,3-diaminopropan-2-ol, in which two binuclear fragments are linked by the malonate dianion, is synthesized. The exchange interaction in the binuclear clusters is shown to be antiferromagnetic (2J = −59 cm−1), whereas the intercluster interaction is ferromagnetic (zJ’ = 7.5 cm−1). The structure of the DMSO solvate of the complex is determined by X-ray diffraction analysis.

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Copyright information

© Pleiades Publishing, Ltd. 2013

Authors and Affiliations

  • L. D. Popov
    • 1
  • S. I. Levchenkov
    • 2
  • I. N. Shcherbakov
    • 1
  • K. Yu. Suponitskii
    • 3
  • A. S. Burlov
    • 1
  • S. S. Beloborodov
    • 1
  • V. V. Lukov
    • 1
  • V. A. Kogan
    • 1
  1. 1.Southern Federal UniversityRostov-on-DonRussia
  2. 2.Southern Scientific CenterRussian Academy of SciencesRostov-on-DonRussia
  3. 3.Nesmeyanov Institute of Organoelement CompoundsRussian Academy of SciencesMoscowRussia

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