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Synthesis, structures, and thermolysis of new heterometallic cobalt, nickel, and copper complexes with the [Ru(NO)(NO2)4(OH)]2− anion as a ligand

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Abstract

Heterometallic complexes with pyridine-N-oxide (PyO), Ru(NO)(NO2)4(OH)Ni(PyO)2(H2O)] · CH3COCH3 (I), [{Ru(NO)(NO2)2(μ-NO2)2(μ-OH)Co}2(μ-PyO)] · H2O · CH3COCH (II), and [Ru(NO)(NO2)4(OH)Cu(PyO)2 (III), are isolated in the reactions of Na2[Ru(NO)(NO2)4(OH)] with nitrates of the corresponding metals in the presence of the organic ligand. The compounds synthesized are characterized by IR spectra, thermal analysis, and X-ray diffraction analysis. Depending on the M2+ cation, the ruthenium cation is coordinated through the bidentate (III, Cu2+) or tridentate (I, Ni2+ and II, CO2+) mode involving the bridging OH group and one or two NO2 groups. The thermal decomposition of complex II results in the formation of a Co0.5Ru0.5 solid solution, which is thermodynamically stable under the decomposition conditions. The thermolysis of complexes I and III in a hydrogen atmosphere leads to the formation of metastable solid solutions.

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Authors and Affiliations

  1. Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, pr. akademika Lavrent’eva 3, Novosibirsk, 630090, Russia

    G. A. Kostin, A. O. Borodin, N. V. Kurat’eva & E. Yu. Semitut

  2. Novosibirsk State University, ul. Pirogova 2, Novosibirsk, 630090, Russia

    G. A. Kostin & N. V. Kurat’eva

Authors
  1. G. A. Kostin
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  2. A. O. Borodin
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  3. N. V. Kurat’eva
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  4. E. Yu. Semitut
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Correspondence to G. A. Kostin.

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Original Russian Text © G.A. Kostin, A.O. Borodin, N.V. Kurat’eva, E.Yu. Semitut, 2013, published in Koordinatsionnaya Khimiya, 2013, Vol. 39, No. 4, pp. 244–250.

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Kostin, G.A., Borodin, A.O., Kurat’eva, N.V. et al. Synthesis, structures, and thermolysis of new heterometallic cobalt, nickel, and copper complexes with the [Ru(NO)(NO2)4(OH)]2− anion as a ligand. Russ J Coord Chem 39, 353–359 (2013). https://doi.org/10.1134/S1070328413040064

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  • DOI: https://doi.org/10.1134/S1070328413040064

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