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Hydrothermal synthesis and structural characterization of a new one-dimensional ladder-shaped metal-organic framework Zn(HTci)(4,4′-bipy)0.5 · H2O (H3Tci = tri(2-carboxyethyl)isocyanurate, 4,4′-bipy = 4,4′-bipyridine)

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Abstract

A new metal-organic coordination polymer, namely, Zn(HTci)(4,4′-Bipy)0.5 · H2O (I) (H3Tci = tri(2-carboxyethyl)isocyanurate, 4,4′-Bipy = 4,4′-bipyridine), has been synthesized under hydrothermal conditions by the reaction of zinc nitrate, H3Tci, and 4,4′-Bipy with the presence of H2O and characterized by elemental analysis, IR and X-ray single-crystal diffraction. The X-ray diffraction analysis reveals that I crystallizes in the triclinic system, \(P\bar 1\) space group. The unit cell parameters for I: a = 5.248(1), b = 12.537(2), c = 14.597(2) Å, α = 91.91(1)°, β = 91.22(2)°, γ = 95.75(1)°, V = 954.8(3) Å3, Z = 2.

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Authors and Affiliations

  1. Key Laboratory of Evidence Science (China University of Political Science and Law), Ministry of Education, Beijing, 100088, P.R. China

    L. Cui

  2. Department of Document Examination, China Criminal Police University, Shenyang, 110854, P.R. China

    L. Cui

  3. Department of Forensic Chemistry, China Criminal Police University, Shenyang, 110854, P.R. China

    P. Ch. Zhao

Authors
  1. L. Cui
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  2. P. Ch. Zhao
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Correspondence to P. Ch. Zhao.

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Cui, L., Zhao, P.C. Hydrothermal synthesis and structural characterization of a new one-dimensional ladder-shaped metal-organic framework Zn(HTci)(4,4′-bipy)0.5 · H2O (H3Tci = tri(2-carboxyethyl)isocyanurate, 4,4′-bipy = 4,4′-bipyridine). Russ J Coord Chem 39, 316–320 (2013). https://doi.org/10.1134/S1070328413040040

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  • DOI: https://doi.org/10.1134/S1070328413040040

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