Russian Journal of Coordination Chemistry

, Volume 39, Issue 2, pp 225–228 | Cite as

Synthesis, crystal structure, and thermal stability of 1D coordination polymer [Zn(BDOA)(Py)2(H2O)]n

  • L. J. Li
  • X. X. Hua
  • G. Y. Wang
  • Y. Y. Huang
  • L. Z. Wang
  • C. Tian
  • J. L. Du
Article

Abstract

A new coordination polymer, [Zn(BDOA)(Py)2(H2O)]n (I) (BDOA = benzene-1,4-dioxylacetate, Py = pyridine), has been prepared via self-assembly of benzene-1,4-dioxylacetate with zinc nitrate under mild conditions and characterized by IR spectra, elemental analysis and X-ray diffraction single-crystal analysis. The complex crystallizes in the monoclinic system, space group C2/c with a = 15.5751(9), b = 6.0898(4), c = 21.7133(13) Å, V = 1991.9(2) Å3, β = 104.719(1)°, Z = 4. The zinc atoms are bridged by BDOA ligand, forming a one-dimensional chain along the z axis. A two-dimensional layer structure is formed by the intermolecular hydrogen bonds. The thermal decomposition profile of the complex is reported as well.

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. 1.
    Bradshaw, D., Claridge, J.B., Cussen, E.J., et al., Acc. Chem. Res., 2005, vol. 38, p. 273.CrossRefGoogle Scholar
  2. 2.
    Feijie Song, Cheng Wang, Falkowski, J.M., et al., J. Am. Chem. Soc., 2010, vol. 132, p. 15390.CrossRefGoogle Scholar
  3. 3.
    Bingbing Ding, Yanqing Weng, Zongwan Mao, et al., Inorg. Chem., 2005, vol. 44, p. 8836.CrossRefGoogle Scholar
  4. 4.
    Eun Young Lee, Seung Yeon Jang, and Myunghyun Paik Suh, J. Am. Chem. Soc., 2005, vol. 127, p. 6374.CrossRefGoogle Scholar
  5. 5.
    Zheng He, Enqing Gao, Zheming Wang, et al., Inorg. Chem., 2005, vol. 44, p. 862.CrossRefGoogle Scholar
  6. 6.
    Long Pan, Nengwu Zheng, Yonggang Wu, et al., Inorg. Chem., 2001, vol. 40, p. 828.CrossRefGoogle Scholar
  7. 7.
    Reineke, T.M., Eddaoudi, M., Fehr, M., et al., J. Am. Chem. Soc., 1999, vol. 121, p. 1651.CrossRefGoogle Scholar
  8. 8.
    Xiangjun Zheng, Linpei Jin, and Shaozhe Lu, Inorg. Chem., 2002, p. 3356.Google Scholar
  9. 9.
    Kiritsis, V., Michaelides, A., Skoulika, S., et al., Inorg. Chem., 1998, vol. 37, p. 3407.CrossRefGoogle Scholar
  10. 10.
    Pan, L., Adams, K.M., Hernandez, H.E., et al., J. Am. Chem. Soc., 2003, vol. 125, p. 3062.CrossRefGoogle Scholar
  11. 11.
    Clegg, W., Cressey, J.T., McCamley, A., and Straughan, B.P., Acta Crystallogr., Sect. C: Cryst. Struct. Commun., 1995, vol. 51, p. 234.CrossRefGoogle Scholar

Copyright information

© Pleiades Publishing, Ltd. 2013

Authors and Affiliations

  • L. J. Li
    • 1
  • X. X. Hua
    • 1
  • G. Y. Wang
    • 1
  • Y. Y. Huang
    • 1
  • L. Z. Wang
    • 1
  • C. Tian
    • 1
  • J. L. Du
    • 1
  1. 1.Key Laboratory of Medicinal Chemistry and Molecular DiagnosisHebei UniversityBaodingP.R. China

Personalised recommendations