Russian Journal of Coordination Chemistry

, Volume 39, Issue 2, pp 201–208 | Cite as

Manganese(III) complexes with tetradentate (N2O2) Schiff bases and dicyanamide

  • V. A. Kopotkov
  • S. V. Simonov
  • A. V. Sadakov
  • E. B. Yagubskii


New Mn(III) complexes with Schiff bases and dicyanamide are synthesized: [Mn(Salpn)N(CN)2] n (two polymorphous modifications, Ia and Ib), {[Mn(5-BrSalen)N(CN)2] · CH3OH} n (II), and [Mn(3-MeOSalen)N(CN)2(H2O)] (III), where SalpnH2 = N,N′-bis(salicylidene)-1,3-diaminopropane, 5-BrSalenH2 = N,N′-bis(5-bromosalicylidene)-1,2-diaminoethane, and 3-MeOSalenH2 = N,N′-bis(3-methoxysalicylidene)-1,2-diaminoethane. Complexes Ia, Ib, and II have the polymer structure in which the dicyanamide anion binds the paramagnetic Mn(III) complexes with the Schiff bases into one-dimensional chains. Unlike them, in complex III the monomer units containing water and the dicyanamide anion as terminal ligands form dimers due to hydrogen bonds. The study of the magnetic properties of complexes Ia and II shows a weak antiferromagnetic interaction between the Mn3+ ions through the dicyanamide bridges in these complexes.


Schiff Base Coordination Chemistry Salen Salicylidene Acetate Tetrahydrate 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.


Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.


  1. 1.
    Ashmawy, F.M., McAuliffe, C.A., (Dick) Parish, R.V., and Tames, J., Dalton Trans., 1985, no. 7, p. 1391.Google Scholar
  2. 2.
    Hulme, Ch.E., Watkinson, M., Haynes, M., et al., Dalton Trans., 1997, no. 11, p. 1805.Google Scholar
  3. 3.
    Sakamoto, F., Sumiya, T., Fujita, M., et al., Chem. Lett., 1998, vol. 27, no. 11, p. 1127.CrossRefGoogle Scholar
  4. 4.
    Garcia-Deibe, A., Sousa, A., Bermejo, M.R., et al., Chem. Commun., 1991, no. 8, p. 728.Google Scholar
  5. 5.
    Miyasaka, H., Clerac, R., Ishii, T., et al., Dalton Trans., 2002, no. 7, p. 1528.Google Scholar
  6. 6.
    Lecren, L., Wernsdorfer, W., Lindigni, Y.-G., et al., J. Am. Chem. Soc., 2007, vol. 129, no. 16, p. 5045.CrossRefGoogle Scholar
  7. 7.
    Shyu, H.-L., Wei, H.-H., and Wang, Yu., Inorg. Chim. Acta, 1999, vol. 290, no. 1, p. 8.CrossRefGoogle Scholar
  8. 8.
    Reddy, K.R., Rajasekharan, M.V., and Tuchagues, J.-P., Inorg. Chem., 1998, vol. 37, no. 23, p. 5978.CrossRefGoogle Scholar
  9. 9.
    Li, H., Zhong, Zh.J., Duan, Ch.-Y., et al., Inorg. Chim. Acta, 1998, vol. 271, nos. 1–2, p. 99.CrossRefGoogle Scholar
  10. 10.
    Khalaji, A.D. and Ng, S.W., Russ. Chem. Coord. Chem., 2011, vol. 37, no. 1, p. 26.CrossRefGoogle Scholar
  11. 11.
    Matsumoto, N., Sunatsuki, Y., Miyasaka, H., et al., Angew. Chem., Int. Ed. Engl., 1999, vol. 38, no. 12, p. 171.CrossRefGoogle Scholar
  12. 12.
    Natase, S., Tuna, F., Maxim, C., et al., Cryst. Growth Des., 2007, vol. 7, no. 9, p. 1825.CrossRefGoogle Scholar
  13. 13.
    Lu, Z., Yuan, M., Pan, F., et al., Inorg. Chem., 2006, vol. 45, no. 9, p. 3538.CrossRefGoogle Scholar
  14. 14.
    Sailaja, S., Reddy, K.R., Rajasekharan, M.V., et al., Inorg. Chem., 2003, vol. 42, no. 1, p. 180.CrossRefGoogle Scholar
  15. 15.
    Choi, H.-L., Sokol, J.J., and Long, J.R., Inorg. Chem., 2004, vol. 43, no. 5, p. 1606.CrossRefGoogle Scholar
  16. 16.
    Zhou, H.-B., Wang, J., Wang, H.-Sh., et al., Inorg. Chem., 2011, vol. 50, no. 15, p. 6868.CrossRefGoogle Scholar
  17. 17.
    Ababei, R., Li, Y.-G., Roubeau, O., et al., New J. Chem., 2009, vol. 33, no. 6, p. 1237.CrossRefGoogle Scholar
  18. 18.
    Ferbinteanu, M., Miyasaka, H., Wernsdorfer, W., et al., J. Am. Chem. Soc., 2005, vol. 127, no. 9, p. 3090.CrossRefGoogle Scholar
  19. 19.
    Pan, F., Wang, Z.-M., and Gao, S., Inorg. Chem., 2007, vol. 46, no. 24, p. 10221.CrossRefGoogle Scholar
  20. 20.
    Sun, H.-L., Wang, Z.-M., and Gao, S., Coord. Chem. Rev., 2010, vol. 254, nos. 1–2, p. 1081.CrossRefGoogle Scholar
  21. 21.
    Manson, J.L., Kmety, C.R., Huang, Q.Z., et al., Chem. Mater., 1998, vol. 10, no. 9, p. 2552.CrossRefGoogle Scholar
  22. 22.
    Kurmoo, M. and Kepert, C., New J. Chem., 1998, vol. 22, no. 12, p. 1515.CrossRefGoogle Scholar
  23. 23.
    Batten, S.R., Jensen, P., Kepert, C.J., et al., Dalton Trans., 1999, no. 24, p. 2987.Google Scholar
  24. 24.
    Van der Werff, P., Batten, S.R., Jensen, P., et al., Polyhedron, 2001, vol. 20, nos. 11–14, p. 1129.CrossRefGoogle Scholar
  25. 25.
    Van der Werff, P.M., Batten, S.R., Jensen, P., et al., Cryst. Growth Des., 2004, vol. 4, no. 3, p. 503.CrossRefGoogle Scholar
  26. 26.
    Schlueter, J.A., Manson, J.L., and Geiser, U., Inorg. Chem., 2005, vol. 44, no. 9, p. 3194.CrossRefGoogle Scholar
  27. 27.
    Shi, Q., Cao, R., Li, X., et al., New J. Chem., 2002, vol. 26, no. 10, p. 1397.CrossRefGoogle Scholar
  28. 28.
    Price, D.J., Batten, S.R., Moubaraki, B., and Murray, K.S., Indian J. Chem., Sect. A: Inorg., Bioinorg., Phys., Theor. Anal. Chem., 2003, vol. 42, p. 2256.Google Scholar
  29. 29.
    Batten, S.R., Jensen, P., Moubaraki, B., et al., Chem. Commun., 1998, no. 3, p. 439.Google Scholar
  30. 30.
    Kmety, C.R.Q., Huang, Q., Jeffrey, W., et al., Phys. Rev., 2000, vol. 62, no. 9, p. 5576.CrossRefGoogle Scholar
  31. 31.
    Nakamoto, K., Infrared Spectra and Raman Spectra of Inorganic and Coordination Compounds, New York: Wiley, 1986.Google Scholar
  32. 32.
    CrysAlisPro. Agilent Technologies. Version 2011.Google Scholar
  33. 33.
    Burla, M.C., Caliandro, R., Camalli, M., et al., J. Appl. Crystallogr., 2005, vol. 38, p. 381.CrossRefGoogle Scholar
  34. 34.
    Palatinus, L. and Chapuis, G., J. Appl. Crystallogr., 2007, vol. 40, p. 786.CrossRefGoogle Scholar
  35. 35.
    Sheldrick, G.M., Acta Crystallogr., Sect. A: Found. Crystallogr., 2008, vol. 64, p. 112.CrossRefGoogle Scholar

Copyright information

© Pleiades Publishing, Ltd. 2013

Authors and Affiliations

  • V. A. Kopotkov
    • 1
  • S. V. Simonov
    • 2
  • A. V. Sadakov
    • 3
  • E. B. Yagubskii
    • 1
  1. 1.Institute of Problems of Chemical PhysicsRussian Academy of SciencesChernogolovka, Moscow oblastRussia
  2. 2.Institute of Solid State PhysicsRussian Academy of SciencesChernogolovka, Moscow oblastRussia
  3. 3.Lebedev Physical InstituteRussian Academy of SciencesMoscowRussia

Personalised recommendations