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Syntheses and structures of p-HOOCC6F4COOH · H2O (H2L · H2O) and luminescent coordination polymers [Tb2(H2O)4(L)3 · 2H2O] n and Tb2(Phen)2(L)3 · 2H2O

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Abstract

Compounds p-HOOCC6F4COOH · H2O (H2L · H2O), [Tb2(H2O)4(L)3 · 2H2O] n (I), and Tb2(Phen)2(L)3 · 2H2O (II) are synthesized. According to the X-ray structure analysis data, the crystal structure of H2L · H2O is built of centrosymmetric molecules H2L and molecules of water of crystallization. The crystal structure of compound I is built of layers of coordination 2D polymer [Tb2(H2O)4(L)3] n and molecules of water of crystallization. The ligands are the L2− anions performing both the tetradentate bridging and pentadentate bridging-chelating functions. The coordination polyhedron TbO9 is a distorted three-capped trigonal prism. Acid H2L manifests photoluminescence in the UV region (λmax = 368 nm). Compounds I and II have the green luminescence characteristic of the Tb3+ ions, and the band with λmax = 545 nm (transition 5 D 4→ 7 F 5) is maximum in intensity. The photoluminescence intensity of compound II is higher than that for compound I.

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Authors and Affiliations

  1. Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, pr. Akad. Lavrent’eva 3, Novosibirsk, 630090, Russia

    S. V. Larionov, L. I. Myachina, L. A. Glinskaya, I. V. Korol’kov, E. M. Uskov & O. V. Antonova

  2. Vorozhtsov Institute of Organic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, 630090, Russia

    V. M. Karpov, V. E. Platonov & V. P. Fadeeva

Authors
  1. S. V. Larionov
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  2. L. I. Myachina
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  3. L. A. Glinskaya
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  4. I. V. Korol’kov
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  5. E. M. Uskov
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  6. O. V. Antonova
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  7. V. M. Karpov
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  8. V. E. Platonov
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  9. V. P. Fadeeva
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Correspondence to S. V. Larionov.

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Original Russian Text © S.V. Larionov, L.I. Myachina, L.A. Glinskaya, I.V. Korol’kov, E.M. Uskov, O.V. Antonova, V.M. Karpov, V.E. Platonov, V.P. Fadeeva, 2012, published in Koordinatsionnaya Khimiya, 2012, Vol. 38, No. 12, pp. 827–833.

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Larionov, S.V., Myachina, L.I., Glinskaya, L.A. et al. Syntheses and structures of p-HOOCC6F4COOH · H2O (H2L · H2O) and luminescent coordination polymers [Tb2(H2O)4(L)3 · 2H2O] n and Tb2(Phen)2(L)3 · 2H2O. Russ J Coord Chem 38, 717–723 (2012). https://doi.org/10.1134/S1070328412110036

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  • DOI: https://doi.org/10.1134/S1070328412110036

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