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Supramolecular structure of tetraaquabis[1-(carboxylatomethyl)-1,3-benzimidazol-3-ium-3-acetato-κO] Cadmium(II) dehydrate

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Abstract

A new complex, [Cd(C11H9N2O4)2(H2O)4]·2H2O, was synthesized and studied by X-ray diffraction analysis. The central Cd(II) atom lies on a crystallographic inversion center and is coordinated by four water molecules and two monodentate 1-(carboxymethyl)-1,3-benzimidazol-3-ium-3-acetate ligands in a slightly distorted octahedral geometry. The crystal packing is stabilized by intermolecular O-H…O hydrogen bonds, which generate a three-dimensional framework.

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Authors and Affiliations

  1. College of Pharmaceutical and Chemical Engineering, Taizhou University, Linhai, Zhejiang, 317000, P.R. China

    Z. L. Zhang, L. Huang, C. F. Wang & Y. L. Wang

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  1. Z. L. Zhang
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  2. L. Huang
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  3. C. F. Wang
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  4. Y. L. Wang
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Correspondence to Z. L. Zhang.

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Zhang, Z.L., Huang, L., Wang, C.F. et al. Supramolecular structure of tetraaquabis[1-(carboxylatomethyl)-1,3-benzimidazol-3-ium-3-acetato-κO] Cadmium(II) dehydrate. Russ J Coord Chem 38, 620–622 (2012). https://doi.org/10.1134/S1070328412090084

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  • DOI: https://doi.org/10.1134/S1070328412090084

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