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A 1D double chains architecture based on the pyridine-2-sulfonate, 4,4′-Bipyridine and acetate-bridged of Zn(II) complex: Synthesis, spectral, thermal properties, and crystal structure

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Abstract

A new 1D double chains Zn(II) supramolecule framework, {[Zn2(2-pSO3)2(Ac)2(4,4′-Bipy)2](4,4′-Bipy)} n (I) (2-pSO3H = pyridine-2-sulfonate, 4,4′-Bipy = 4,4′-bipyridine), was synthesized by reaction of Zn(CH3COO)2 · 2H2O in methanol-water mixed solution and characterized by X-ray diffraction, elemental analysis, and IR spectrum. X-ray analysis indicates that I is a coordination polymer in which two deprotonated 2-pSO3H through the aromatic nitrogens in trans positions, oxygens in cis positions and two N atoms of 4,4′-Bipy and two μ2-Ac− ligands, resulting in a ZnN3O3 distorted octahedral geometry. The 1D coordination polymer was connected to 2D and 3D supramolecule framework via π-stacking and weak C-H…O contacts. The complex I also displays strong fluorescence property and good thermal stability.

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References

  1. Haw-thorne, M.F. and Zheng, Z., Acc. Chem. Res., 1997, vol. 30, p. 267.

    Article  CAS  Google Scholar 

  2. Eddaoudi, M., Moler, D.B., Li, H., et al., Acc. Chem. Res., 2001, vol. 34, 319.

  3. Yaghi, O.M., Li, H.L., Davis, C., et al., Acc. Chem. Res., 1998, vol. 31, p. 474.

    Article  CAS  Google Scholar 

  4. Moulton, B. and Zaworotko, M., Chem. Rev., 2001, vol. 101, p. 1629.

    Article  CAS  Google Scholar 

  5. Kitagawa, S. and Uemura, K., Chem. Soc. Rev., 2005, vol. 34, p. 109.

    Article  CAS  Google Scholar 

  6. Côé, A.P. and Shimazu, G.K.H., Chem. Eur. J., 2003, vol. 9, p. 5361.

    Article  Google Scholar 

  7. Côé, A.P. and Shimazu, G.K.H., Coord. Chem. Rev., 2003, vol. 245, p. 49.

    Article  Google Scholar 

  8. Burkholder, E., Golub, V., O’Connor, C.J., and Zubieta, J., Chem. Commun., 2003, vol. 20, p. 2128.

    Article  Google Scholar 

  9. Finn, E., Burkholder, R.C., and Zubieta, J., Chem. Commun., 2001, vol. 18, p. 1852.

    Article  Google Scholar 

  10. Finn, R.C. and Zubieta, J., Inorg. Chem., 2001, vol. 40, p. 2466.

    Article  CAS  Google Scholar 

  11. Mao, J.G., Wang, Z., and Clearfield, A., Inorg. Chem., 2002, vol. 41, p. 2334.

    Article  CAS  Google Scholar 

  12. Mao, J.G., Wang, Z., and Clearfield, A., Dalton Trans., 2002, vol. 24, p. 4541.

    Google Scholar 

  13. Mao, J.G., Wang, Z., and Clearfield, A., Inorg. Chem., 2002, vol. 41, p. 3713.

    Article  CAS  Google Scholar 

  14. Mao, J.G., Wang, Z., and Clearfield, A., New J. Chem., 2002, vol. 26, p. 1010.

    Article  CAS  Google Scholar 

  15. Cai, J.W., Coord. Chem. Rev., 2004, vol. 248, p. 1061.

    Article  CAS  Google Scholar 

  16. Hu, S., He, K.H., Zeng, M.H., et al., Inorg. Chem., 2008, vol. 47, p. 5218.

    Article  CAS  Google Scholar 

  17. Jiang, Y.M., Zheng, Y., He, K.H., et al., Inorg. Chem., 2011, vol. 50, p. 2329.

    Article  CAS  Google Scholar 

  18. Sheldrick, G.M., SHELXL-97, Program for the Refinement of X-ray Crystal Structures, Göttingen (Germany): Univ. of Göttingen, 1997.

    Google Scholar 

  19. Sheldrick, G.M., SHELXS-97, Program for Crystal Structure Solution, Göttingen (Germany): Univ. of Göttingen, 1997.

    Google Scholar 

  20. Cai, J., Chen, C.H., Liao, C.Z., et al., Dalton Trans., 2001, vol. 9, p. 1137.

    Google Scholar 

  21. Liu, Q.Y., Wang, Y.L., and Xu, L., Eur. J. Inorg. Chem., 2006, vol. 31, p. 4843.

    Article  Google Scholar 

  22. Huang, X.Y. and Li, J., J. Am. Chem. Soc., 2007, vol. 129, p. 3157.

    Article  CAS  Google Scholar 

  23. Wei, K.J., Ni, J., Xie, Y.S., et al., Inorg. Chem. Commun., 2007, vol. 10, p. 279.

    Article  CAS  Google Scholar 

  24. Chang, Z., Zhang, A.S., Hu, T.L., et al., Cryst. Growth Des., 2009, vol. 9, p. 4840.

    Article  CAS  Google Scholar 

  25. Li, C.P., Yu, Q., Chen, J., et al., Cryst. Growth Des., 2010, vol. 10, p. 2650.

    Article  CAS  Google Scholar 

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Authors and Affiliations

  1. College of Chemistry and Chemical Engineering, Qinzhou University, Qinzhou, Guangxi, 535000, P.R. China

    Z. F. Shi, J. M. Li & K. H. He

  2. College of Chemistry and Chemical Engineering, Guangxi Normal University Guilin, Guangxi, 541004, PR. China

    Y. M. Jiang

Authors
  1. Z. F. Shi
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  2. J. M. Li
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  3. K. H. He
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  4. Y. M. Jiang
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Correspondence to J. M. Li or Y. M. Jiang.

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Shi, Z.F., Li, J.M., He, K.H. et al. A 1D double chains architecture based on the pyridine-2-sulfonate, 4,4′-Bipyridine and acetate-bridged of Zn(II) complex: Synthesis, spectral, thermal properties, and crystal structure. Russ J Coord Chem 38, 614–619 (2012). https://doi.org/10.1134/S1070328412080064

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  • DOI: https://doi.org/10.1134/S1070328412080064

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