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A new 2D rhombic network metal-organic framework: (H3O+)[In(Tbip)2] · H2O (H2Tbip = 5-tert-butylisophthalic acid)

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Abstract

A new coordination polymer (H3O+)[In(Tbip)2] · H2O (I) (H2Tbip is 5-tert-butylisophthalic acid) has been synthesized under hydrothermal conditions. Complex I has been characterized by elemental analysis, IR, TG analysis, and powder X-ray diffraction. Single-crystal X-ray diffraction studies revealed that I crystallizes in the monoclinic crystal system, space group C2/c. In I the metal centers are linked by bridging Tbip ligand to form an interesting extended two-dimensional rhombic network.

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Authors and Affiliations

  1. College of Chemistry, Liaoning University, Shenyang, 110036, P.R. China

    Y. Q. Xu, J. W. Ji & Z. B. Han

  2. Pharmaceutic College, Liaoning University, Shenyang, 110036, P.R. China

    X. F. Wang

Authors
  1. Y. Q. Xu
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  2. X. F. Wang
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  3. J. W. Ji
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  4. Z. B. Han
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Correspondence to Z. B. Han.

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Xu, Y.Q., Wang, X.F., Ji, J.W. et al. A new 2D rhombic network metal-organic framework: (H3O+)[In(Tbip)2] · H2O (H2Tbip = 5-tert-butylisophthalic acid). Russ J Coord Chem 37, 748–751 (2011). https://doi.org/10.1134/S1070328411100149

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  • DOI: https://doi.org/10.1134/S1070328411100149

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