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A new 1D chiral metal-organic coordination polymer constructed by Cu(II) with L-3-Cyanophenylalanine

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Abstract

A new 1D chiral metal-organic coordination polymer [Cu(Cphe)2] · 3H2O (I) (HCphe = L-3-Cyanophenylalanine) has been synthesized in an aqueous solution and characterized by elemental analysis, thermogravimetric analysis (TGA), X-ray powder diffraction (XRPD), infrared spectroscopy (IR) and single crystal X-ray diffraction. The X-ray diffraction analysis reveals that I crystallizes in the monoclinic space group P21. The adjacent copper(II) atoms are linked by Cphe ligands to form a 1D zigzag chain, which is further connected via strong hydrogen bonds to form a 3D supramolecular framework. The unit cell parameters for I are: a = 12.0201(8), b = 6.1495(4), c = 14.8576(10) Å, β = 94.1720(10)°, V = 1095.00(13) Å3, and Z = 2.

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Authors and Affiliations

  1. College of Chemistry, Liaoning University, Shenyang, 110036, P.R. China

    Y. E. Du & Z. B. Han

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  1. Y. E. Du
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  2. Z. B. Han
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Correspondence to Z. B. Han.

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Du, Y.E., Han, Z.B. A new 1D chiral metal-organic coordination polymer constructed by Cu(II) with L-3-Cyanophenylalanine. Russ J Coord Chem 37, 594–599 (2011). https://doi.org/10.1134/S1070328411070049

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  • DOI: https://doi.org/10.1134/S1070328411070049

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