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Synthesis and crystal structure of a cyanide-bridged one-dimensional nickel(II) complex with alternating [Ni(En)2]2+ and [Ni(CN)4]2− ions

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Abstract

The complex [Ni(En)2][Ni(CN)4] · 3.5H2O (I) (En = ethylenediamine) was synthesized by the reaction of [Ni(En)2](ClO4)2 and K2[Ni(CN)4] in an H-shaped tube. The crystal structure of I has been determined by single-crystal X-ray analysis. The crystal of complex I is orthorhombic, space group Pnna with a = 28.151(3), b = 8.3946(8), c = 14.5441(13)Å, M =404.76, Z = 8, V = 3437.0(5)Å3. The structure of complex I reveals infinite zigzag chains shaped structure are formed by cis-Ni(En)2-μ-(NC)2, cis-μ-(NC)2Ni(CN)2, and trans-μ-(CN)2Ni(En)2.

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References

  1. Dunbar, K.R. and Heintz, R.A., Prog. Inorg. Chem., 1997, vol. 45, p. 283.

    Article  CAS  Google Scholar 

  2. Verdaguer, M., Bleuzen, A., Marcaud, V., et al., Coord. Chem. Rev., 1999, vol. 190, p. 1023.

    Article  Google Scholar 

  3. Ohba, M. and Okawa, H., Coord. Chem. Rev., 2000, vol. 198, p. 313.

    Article  CAS  Google Scholar 

  4. Pinkowicz, D., Podgajny, R., Nitek, W., et al., Inorg. Chim. Acta, 2008, vol. 361, p. 3957.

    Article  CAS  Google Scholar 

  5. Kou, H.Z., Zhou, B.C., Liao, D.Z., et al., Inorg. Chem., 2002, vol. 41, no. 25, p. 6887.

    Article  CAS  Google Scholar 

  6. Gu, Z.Z., Sato, O., Iyoda, T., et al., Chem. Mater., 1997, vol. 9, no. 5, p. 1092.

    Article  CAS  Google Scholar 

  7. Yet, L., Angew. Chem. Int. Ed., 2001, vol. 40, no. 5, p. 875.

    Article  CAS  Google Scholar 

  8. Zhan, S.Z., Guo, D., Zhang, X.Y., et al., Inorg. Chim. Acta, 2000, vol. 298, p. 57.

    Article  CAS  Google Scholar 

  9. Kou, H.Z., Liao, D.Z., Jiang, Z.H., et al., Inorg. Chem. Commun., 2000, vol. 3, p. 151.

    Article  CAS  Google Scholar 

  10. Akitsu, T. and Einaga, Y., Inorg. Chem., 2006, vol. 45, no. 24, p. 9826.

    Article  CAS  Google Scholar 

  11. Rodriguez, A., Sakiyama, H., Masciocchi, N., et al., Inorg. Chem., 2005, vol. 44, no. 23, p. 8399.

    Article  CAS  Google Scholar 

  12. Kou, H.Z., Gao, S., Sun, B.W., and Zhang, J., Chem. Mater., 2001, vol. 13, no. 5, p. 1431.

    Article  CAS  Google Scholar 

  13. Kajňaková, M., Černák, J., Kavečanský, V., et al., Solid State Sci., 2006, vol. 8, p. 203.

    Article  Google Scholar 

  14. Wang, R., Xia, H., and Nie, L.B., Russ. J. Coord. Chem., 2009, vol. 35, no. 10, p. 720.

    Article  CAS  Google Scholar 

  15. Cao, H.M., Handbook of Inorganic Compounds’ Synthesis, China, 1988.

  16. Sheldrick, G.M., SHELX-97, Göttingen (Germany): Univ. of Göttingen, 1997.

    Google Scholar 

  17. Sharpe, A.G., The Chemistry of the Cyano Complexes of the Transition Metals, London: Academic, 1976.

    Google Scholar 

  18. Ribas, J., Casabó, J., Serra, M., and Coronas, J.M., Inorg. Chim. Acta, 1979, vol. 36, p. 41.

    Article  CAS  Google Scholar 

  19. Ribas, J., Serra, M., Escuer, A., and Coronas, J.M., J. Inorg. Nucl. Chem., 1981, vol. 43, no. 12, p. 3113.

    Article  CAS  Google Scholar 

  20. Shriver, D.F. and Posner, J., J. Am. Chem. Soc., 1966, vol. 88, no. 8, p. 1672.

    Article  CAS  Google Scholar 

  21. Zhou, H.B., Dong, W., Zhu, L.N., et al., J. Mol. Struct., 2004, vol. 703, p. 103.

    Article  CAS  Google Scholar 

  22. Yuge, H., Mamada, A., Asai, M., et al., J. Chem. Soc., Dalton Trans., 1995, no. 1, p. 3195.

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Authors and Affiliations

  1. Faculty of Material Science and Chemistry Engineering, China University of Geosciences, Wuhan, 430074, P.R. China

    B. Tao, H. Xia, X. Jiang & Y. F. Zhu

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  1. B. Tao
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  2. H. Xia
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  3. X. Jiang
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  4. Y. F. Zhu
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Correspondence to H. Xia.

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Tao, B., Xia, H., Jiang, X. et al. Synthesis and crystal structure of a cyanide-bridged one-dimensional nickel(II) complex with alternating [Ni(En)2]2+ and [Ni(CN)4]2− ions. Russ J Coord Chem 37, 367–370 (2011). https://doi.org/10.1134/S1070328411040099

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  • DOI: https://doi.org/10.1134/S1070328411040099

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