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Hydrothermal synthesis and crystal structure of a new 2D metal-organic framework: [Zn(Btca)(Phen)] n (H2Btca = benzotriazole-5-carboxylic acid, phen = 1,10-phenanthroline)

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Abstract

A new coordination polymer, [Zn(Btca)(Phen)] n (I) (H2Btca = benzotriazole-5-carboxylic acid, Phen = 1,10-phenanthroline), has hydrothermally been synthesized by the reaction of zinc nitrate, H2Btca and Phen in the presence of DMF and H2O. Single-crystal X-ray diffraction analysis reveals that in complex I the metal centers are linked by the bridging Btca ligand to form an extended two-dimensional wave-like layer decorated by Phen.

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Authors and Affiliations

  1. College of Chemistry, Liaoning University, Shenyang, 110036, P.R. China

    R. Y. Lu & Z. B. Han

  2. Key Laboratory of Polyoxometalate Science of Ministry of Education, Northeast Normal University, Changchun, 130024, P.R. China

    Z. B. Han

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  1. R. Y. Lu
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  2. Z. B. Han
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Correspondence to Z. B. Han.

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Lu, R.Y., Han, Z.B. Hydrothermal synthesis and crystal structure of a new 2D metal-organic framework: [Zn(Btca)(Phen)] n (H2Btca = benzotriazole-5-carboxylic acid, phen = 1,10-phenanthroline). Russ J Coord Chem 37, 172–175 (2011). https://doi.org/10.1134/S1070328411020047

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  • DOI: https://doi.org/10.1134/S1070328411020047

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