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Cucurbit[8]uril-based inclusion compounds containing iron(II), cobalt(III), and nickel(II) complexes with cyclam and cyclen as guest molecules: Synthesis and crystal structures

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Abstract

New inclusion compounds containing iron(II), cobalt(III), and nickel(II) complexes with the cyclic polyamine ligands cyclam and cyclen in the macrocyclic cavitand cucurbit[8]uril (CB[8]) were obtained: {trans-[Fe(Cyclam)(CO)(OCHO)]@CB[8]}Cl · 15H2O, {cis-[Co(Cyclen)(H2O)Cl]@CB[8]}Cl2 · 20H2O, and {cis-[Ni(Cyclen)(H2O)Cl]@CB[8]}Cl · 12H2O. According to X-ray diffraction data, the complexes are in the cavity of each CB[8] molecule. The complexes of the above molecular formulas were isolated in the solid state as supramolecular compounds with CB[8] and structurally characterized for the first time.

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References

  1. Hunter, T.M., McNae, I.W., Simpson, D.P., et al., Chem. Eur. J., 2007, vol. 13, p. 40.

    Article  Google Scholar 

  2. Hunter, T.M., Paisey, S.J., Park, H.S., et al., J. Inorg. Biochem., 2004, vol. 98, no. 5, p. 713.

    Article  CAS  Google Scholar 

  3. Liang, X. and Sadler, P.J., Chem. Soc. Rev., 2004, vol. 33, p. 246.

    Article  CAS  Google Scholar 

  4. Grochala, W., Phys. Chem. Chem. Phys., 2006, vol. 8, no. 11, p. 1340.

    Article  CAS  Google Scholar 

  5. Tsarevsky, N.V., Braunecker, W.A., Tang, W., et al., J. Mol. Catal. A, 2006, vol. 257, nos. 1–2, p. 132.

    CAS  Google Scholar 

  6. Hay, R.W. and Govan, N., Transition Met. Chem., 1998, vol. 23, no. 6, p. 721.

    Article  CAS  Google Scholar 

  7. Cabani, S., Ceccanti, N., Pardini, R., et al., Polyhedron, 1999, vol. 18, no. 25, p. 3295.

    Article  CAS  Google Scholar 

  8. Lippold, I., Gorls, H., and Plass, W., Eur. J. Inorg. Chem., 2007, p. 1487.

  9. Forrow, N.J. and Walters, S.J., Biosens. Bioelectron., 2004, vol. 19, no. 7, p. 763.

    Article  CAS  Google Scholar 

  10. Kim, S.Y., Jung, I.S., Lee, E., et al., Angew. Chem., Int. Ed., 2001, vol. 40, p. 2119.

    Article  CAS  Google Scholar 

  11. Mit’kina, T.V., Naumov, D.Yu., Geras’ko, O.A., et al., Izv. Akad. Nauk, Ser. Khim., 2004, p. 2414.

  12. Hart, S.L., Haines, R.I., Decken, A., et al., Inorg. Chim. Acta, 2009, vol. 362, p. 4145.

    Article  CAS  Google Scholar 

  13. Day, A., Arnold, A.P., Blanch, R.J., et al., J. Org. Chem., 2001, vol. 66, p. 8094.

    Article  CAS  Google Scholar 

  14. APEX2 (version 1.08), SAINT (version 7.03), SADABS (version 2.11). Bruker Advanced X-Ray Solutions. Madison (WI, USA): Bruker AXS Inc., 2004.

  15. Sheldrick, G.M., Acta Crystallogr., Sect. A: Found. Crystallogr., 2008, vol. 64, p. 112.

    Article  Google Scholar 

  16. Kim, K., Selvapalam, N., Ko, Y.H., et al., Chem. Soc. Rev., 2007, vol. 36, p. 267.

    Article  CAS  Google Scholar 

  17. Nakomoto, K., Infrared Spectra of Inorganic and Coordination Compounds, London: Wiley, 1963.

    Google Scholar 

  18. Mitkina, T.V., Sokolov, M.N., Naumov, D.Y., et al., Inorg. Chem., 2006, vol. 45, p. 6950.

    Article  CAS  Google Scholar 

  19. Mitkina, T., Zakharchuk, N., Naumov, D., et al., Inorg. Chem., 2008, vol. 47, p. 6748.

    Article  CAS  Google Scholar 

  20. Marov, I.N. and Kostromina, N.A., YaMR i EPR v Khimii Koordinatsionnykh Soedinenii (NMR and EPR in The Chemistry of Coordination Compounds), Moscow: Nauka, 1979.

    Google Scholar 

  21. Collman, J.P. and Schneider, P.W., Inorg. Chem., 1966, vol. 5, no. 8, p. 1380.

    Article  CAS  Google Scholar 

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Authors and Affiliations

  1. Nikolaev Institute of Inorganic Chemistry, Siberian Division, Russian Academy of Sciences, Novosibirsk, Russia

    E. A. Kovalenko, T. V. Mitkina, O. A. Geras’ko, D. G. Samsonenko, D. Yu. Naumov & V. P. Fedin

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  1. E. A. Kovalenko
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  2. T. V. Mitkina
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  3. O. A. Geras’ko
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  4. D. G. Samsonenko
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  5. D. Yu. Naumov
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  6. V. P. Fedin
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Corresponding author

Correspondence to V. P. Fedin.

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Original Russian Text © E.A. Kovalenko, T.V. Mitkina, O.A. Geras’ko, D.G. Samsonenko, D.Yu. Naumov, V.P. Fedin, 2011, published in Koordinatsionnaya Khimiya, 2011, Vol. 37, No. 3, pp. 163–168.

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Kovalenko, E.A., Mitkina, T.V., Geras’ko, O.A. et al. Cucurbit[8]uril-based inclusion compounds containing iron(II), cobalt(III), and nickel(II) complexes with cyclam and cyclen as guest molecules: Synthesis and crystal structures. Russ J Coord Chem 37, 161–167 (2011). https://doi.org/10.1134/S1070328411020023

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  • DOI: https://doi.org/10.1134/S1070328411020023

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