Complex rhodium(III) salts with isonicotinic acid: Synthesis and study

Abstract

A method for the synthesis of complex rhodium(III) salts of the trans-dichlorotetramine series with isonicotinic acid (iso-NicH) was developed. Three new compounds were isolated: [Rh(iso-NicH)3(iso-Nic)Cl2] (I), [Rh(iso-NicH)4Cl2]Cl · 4H2O (II), and Na3[Rh(iso-Nic)4Cl2] · 9H2O (III). The compounds synthesized were characterized by elemental analysis, X-ray phase analysis, and IR spectroscopy. The crystal structures of salts II and III were determined by X-ray diffraction analysis. The thermal properties of all compounds were studied by the DTA method. The intermediate and final thermolysis products were isolated and characterized.

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Correspondence to D. B. Vasil’chenko.

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Original Russian Text © D.B. Vasil’chenko, A.B. Venediktov, E.Yu. Filatov, I.A. Baidina, P.E. Plyusnin, S. V. Korenev, 2011, published in Koordinatsionnaya Khimiya, 2011, Vol. 37, No. 1, pp. 49–57.

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Vasil’chenko, D.B., Venediktov, A.B., Filatov, E.Y. et al. Complex rhodium(III) salts with isonicotinic acid: Synthesis and study. Russ J Coord Chem 37, 48–56 (2011). https://doi.org/10.1134/S1070328410121061

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Keywords

  • Rhodium
  • Coordination Chemistry
  • Hydroformy Lation
  • Isonicotinic Acid
  • Complex Rhodium