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Synthesis and crystal structure of [W3S4(Acac)3(PPh3)3]PF6 · 0.5CHCl3 and [W3S4(Hfac)3(PPh3)2Br] · 2CHCl3

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Abstract

New cluster complexes [W3S4(Acac)3(PPh3)3]PF6 · 0.5CHCl3 (Acac = CH3C(O)CHC(O)CH3) (I) and [W3S4(Hfac)3(PPh3)2Br] · 2CHCl3 (Hfac = CF3C(O)CHC(O)CF3) (II) were synthesized. Their molecular and crystal structures were determined by X-ray diffraction. The cis-cis type of coordination of acetylacetonate and hexafluoroacetylacetonate ligands in I and II, respectively, was established, and the PPh3 ligands were found in the trans-positions with respect to the “capping” sulfide ligand (μ3-S).

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Authors and Affiliations

  1. Nikolaev Institute of Inorganic Chemistry, Siberian Division, Russian Academy of Sciences, pr. akademika Lavrent’eva 3, Novosibirsk, 630090, Russia

    S. A. Adonin, A. V. Virovets, M. N. Sokolov & V. P. Fedin

  2. Novosibirsk State University, ul. Pirogova 2, Novosibirsk, 630090, Russia

    M. N. Sokolov & V. P. Fedin

Authors
  1. S. A. Adonin
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  2. A. V. Virovets
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  3. M. N. Sokolov
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  4. V. P. Fedin
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Correspondence to S. A. Adonin.

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Original Russian Text © S.A. Adonin, A.V. Virovets, M.N. Sokolov, V.P. Fedin, 2010, published in Koordinatsionnaya Khimiya, 2010, Vol. 36, No. 10, pp. 743–747.

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Adonin, S.A., Virovets, A.V., Sokolov, M.N. et al. Synthesis and crystal structure of [W3S4(Acac)3(PPh3)3]PF6 · 0.5CHCl3 and [W3S4(Hfac)3(PPh3)2Br] · 2CHCl3 . Russ J Coord Chem 36, 734–738 (2010). https://doi.org/10.1134/S1070328410100027

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  • DOI: https://doi.org/10.1134/S1070328410100027

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