Skip to main content
SpringerLink
Log in

Dinuclear complex of gold(III) with 1,3-diaminopropane (HL), [Au2(HL)(L)2](ClO4)3(OH): Synthesis and crystal and molecular structures

  • Published:
Russian Journal of Coordination Chemistry Aims and scope Submit manuscript

Abstract

The dinuclear gold(III) complex, [Au2(HL)(L)2](ClO4)3(OH) (I) (HL = 1,3-diaminopropane), with two amide bridges has been synthesized for the first time. According to the X-ray diffraction data, the crystal structure of complex I consists of the complex cations [Au2(HL)(L)2]4+ and anions ClO −4 and OH−. The coordination sites AuN4 are insignificantly distorted squares. In the four-membered ring Au2N2, the gold atoms are bound by the bridging nitrogen atoms of the deprotonated primary amine.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Puddephatt, R.J., The Chemistry of Gold, Amsterdam: Elsevier, 1978.

    Google Scholar 

  2. Gimeno, M.C. and Laguna, A., Gold Bull., 2003, vol. 36, no. 3, p. 83.

    CAS  Google Scholar 

  3. Cinellu, M.A. and Minghetti, G., Gold Bull., 2002, vol. 35, no. 1, p. 11.

    CAS  Google Scholar 

  4. Adams, H.-N., Grässle, U., Hiller, W., and Strähle, J., Z. Anorg. Allg. Chem., 1983, vol. 504, no. 9, p. 7.

    Article  CAS  Google Scholar 

  5. Grässle, U., Hiller, W., and Strähle, J., Z. Anorg. Allg. Chem., 1985, vol. 529, no. 10, p. 29.

    Article  Google Scholar 

  6. Jones, P.G., Rumpel, H., Schwarzmann, E., and Sheldrick, G.M., Acta Crystallogr., Sect. B: Struct. Crystallogr. Cryst. Chem., 1979, vol. 35, no. 6, p. 1435.

    Article  Google Scholar 

  7. Cinellu, M.A., Minghetti, G., Pinna, M.V., et al., Dalton Trans., 2000, no. 14, p. 1261.

  8. Cinellu, M.A., Minghetti, G., Pinna, M.V., et al., Dalton Trans., 1998, no. 16, p. 1735.

  9. Mundorf, T. and Dehnicke, K., Z. Anorg. Allg. Chem., 1974, vol. 408, no. 2, p. 146.

    Article  CAS  Google Scholar 

  10. McConnell, A.A., Brown, D.H., and Smith, W.E., Spectrochim. Acta, Part A, 1982, vol. 38, no. 2, p. 265.

    Article  Google Scholar 

  11. Messori, L., Abbate, F., Orioly, P., et al., Chem. Commun., 2002, no. 6, p. 612.

  12. Micklitz, W., Lippert, B., Muller, G., et al., Inorg. Chim. Acta, 1989, vol. 165, no. 1, p. 57.

    Article  CAS  Google Scholar 

  13. Mironov, I.V. and Afanas’eva, V.A., Zh. Neorg. Khim., 2010, vol. 55, no. 7, p. 1227 [Russ. J. Inorg. Chem. (Engl. Transl.), vol. 55, no. 7, p. 1156].

    Google Scholar 

  14. Sheldrick, G.M., SHELX-97. Release 97-2, Göttingen (Germany): Univ. of Göttingen, 1998

    Google Scholar 

  15. Weishaupt, M. and Strahle, J., Z. Naturforsch., B: Chem. Sci., 1976, vol. 31, no. 5, p. 554.

    Google Scholar 

  16. Minacheva, L.Kh., Gladkaya, A.Sh., Sakharova, V.G., et al., Zh. Neorg. Khim., 1988, vol. 33, no. 3, p. 683.

    CAS  Google Scholar 

  17. Minacheva, L.Kh., Sadikov, G.G., Sakharova, V.G., et al., Koord. Khim., 1986, vol. 12, no. 10, p. 1417.

    CAS  Google Scholar 

  18. Nardin, G., Randaccio, L., Annibale, G., et al., J. Chem. Soc., Dalton Trans., 1980, no. 2, p. 220.

  19. Rossignoli, M., Bernhardt, P.V., Lawrance, G.A., and Maeder, M., J. Chem. Soc., Dalton Trans., 1997, no. 3, p. 323.

  20. Suh, M.P., Kim, I.S., Shim, B.Y., et al., Inorg. Chem., 1996, vol. 35, no. 12, p. 3595.

    Article  CAS  Google Scholar 

  21. Batsanov, S.S., Zh. Neorg. Khim., 1991, vol. 36, no. 12, p. 3015.

    CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Nikolaev Institute of Inorganic Chemistry, Siberian Division, Russian Academy of Sciences, pr. akademika Lavrent’eva 3, Novosibirsk, 630090, Russia

    V. A. Afanas’eva, L. A. Glinskaya, R. F. Klevtsova & I. V. Mironov

  2. Novosibirsk State University, Novosibirsk, Russia

    I. V. Mironov

Authors
  1. V. A. Afanas’eva
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. L. A. Glinskaya
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. R. F. Klevtsova
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. I. V. Mironov
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to V. A. Afanas’eva.

Additional information

Original Russian Text © V.A. Afanas’eva, L.A. Glinskaya, R.F. Klevtsova, I.V. Mironov, 2010, published in Koordinatsionnaya Khimiya, 2010, Vol. 36, No. 9, pp. 703–709.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Afanas’eva, V.A., Glinskaya, L.A., Klevtsova, R.F. et al. Dinuclear complex of gold(III) with 1,3-diaminopropane (HL), [Au2(HL)(L)2](ClO4)3(OH): Synthesis and crystal and molecular structures. Russ J Coord Chem 36, 697–703 (2010). https://doi.org/10.1134/S1070328410090101

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S1070328410090101

Keywords

Search

Navigation