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Synthesis, crystal structure, and luminescence of a heterotrinuclear Cu2Cd complex containing macrocyclic oxamide and thiocyanate ligands

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Abstract

The complex incorporating macrocyclic oxamide of the formula [(CuL)2Cd(NCS)2] (H2L = 2,3-dioxo-5,6,14,15-dibenzo-1,4,8,12-tetraazacyclo-pentadeca-7,13-diene) has been synthesized and structurally characterized. The crystals crystallize in the monoclinic system, space group C2/c, a = 13.865(3), b = 14.390(3), c = 38.252(8) Å, β = 92.45(3)°, Z = 8. The crystal structure unit is a trianuclear complex in which the Cd2+ and Cu2+ ions are bridged by the macrocyclic oxamide groups. The [(CuL)2Cd(NCS)2] units are alternately bridged by C-H···O to C-H···S hydrogen bond to form a 2D framework. The luminescent property of the compound is also discussed.

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Authors and Affiliations

  1. Tianjin Key Laboratory of Structure and Performance for Functional Molecule, College of Chemistry and Life Science, Tianjin Normal University, Tianjin, 300387, P.R. China

    L. L. Fan, Y. Q. Sun, Y. Y. Xu & D. Z. Gao

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  1. L. L. Fan
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  2. Y. Q. Sun
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  3. Y. Y. Xu
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  4. D. Z. Gao
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Correspondence to Y. Q. Sun.

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Fan, L.L., Sun, Y.Q., Xu, Y.Y. et al. Synthesis, crystal structure, and luminescence of a heterotrinuclear Cu2Cd complex containing macrocyclic oxamide and thiocyanate ligands. Russ J Coord Chem 36, 657–661 (2010). https://doi.org/10.1134/S1070328410090046

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  • DOI: https://doi.org/10.1134/S1070328410090046

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