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Synthesis and crystal structure of [Mo3S4(Dppen)3Cl3]PF6 · 1.5CH2Cl2 and [W3S4(Dppe)3Br3]2ZnBr4 · 5.5CH3CN

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Abstract

New cluster complexes [Mo3S4(Dppen)3Cl3]PF6 · 1.5CH2Cl2 (Dppen = cis-Ph2PCH=CHPPh2) (I) and [W3S4(Dppe)3Br3]2(ZnBr4)2 · 5.5CH3CN (Dppe = Ph2PCH2CH2PPh2) (II) were synthesized. Their molecular and crystal structures were determined by X-ray diffraction. Diphoshine ligands in the complexes I and II are coordinated in the bidentate mode, providing an arrangement of three chelate rings, giving rise to chirality.

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Authors and Affiliations

  1. Nikolaev Institute of Inorganic Chemistry, Siberian Division, Russian Academy of Sciences, pr. akademika Lavrent’eva 3, Novosibirsk, 630090, Russia

    S. A. Adonin, P. A. Abramov, A. V. Virovets, M. N. Sokolov & V. P. Fedin

  2. Novosibirsk State University, ul. Pirogova 2, Novosibirsk, 630090, Russia

    M. N. Sokolov & V. P. Fedin

Authors
  1. S. A. Adonin
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  2. P. A. Abramov
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  3. A. V. Virovets
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  4. M. N. Sokolov
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  5. V. P. Fedin
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Corresponding author

Correspondence to M. N. Sokolov.

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Original Russian Text © S.A. Adonin, P.A. Abramov, A.V. Virovets, M.N. Sokolov, V.P. Fedin, 2010, published in Koordinatsionnaya Khimiya, 2010, Vol. 36, No. 9, pp. 643–649.

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Adonin, S.A., Abramov, P.A., Virovets, A.V. et al. Synthesis and crystal structure of [Mo3S4(Dppen)3Cl3]PF6 · 1.5CH2Cl2 and [W3S4(Dppe)3Br3]2ZnBr4 · 5.5CH3CN. Russ J Coord Chem 36, 637–643 (2010). https://doi.org/10.1134/S1070328410090010

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  • DOI: https://doi.org/10.1134/S1070328410090010

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