Skip to main content
SpringerLink
Log in

Synthesis, crystal structure, and magnetic properties of 2D coordination polymer “[Mn(PDB)(H2O)2] · H2O” n

  • Published:
Russian Journal of Coordination Chemistry Aims and scope Submit manuscript

Abstract

A coordination polymer “[Mn(PDB)(H2O)2] · H2O” n (I) (H2PDB = pyridine-3,4-dicarboxylic acid) was hydrothermally synthesized and characterized by elemental analysis, IR and single-crystal X-ray diffraction. The crystal of complex I are triclinic: C7H9NMnO7, M = 274.09; a = 7.2389(18), b = 8.045(2), c = 9.157(2) Å, α = 75.421(12)° β = 68.092(9)°, γ = 76.021(12)°, V = 1472.3(2) Å3, Z = 2, ρ c = 1.927 g/cm3, μ = 1.420 mm−1, space group P \( \bar 1 \) F(000) = 278, R = 0.0253 and wR = 0.0621 for 1709 observed reflections (I>2σ(I)). X-ray diffraction structure analyses reveal that two-dimensional layers were formed as bridged by PDB, and further assembled into the three-dimensional framework supramolecular structure via hydrogen bonding interaction. Magnetic susceptibility measurements reveal an antiferromagnetic interaction in I.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Braga, D., and Grepioni, F., Coord. Chem. Rev., 1999, vol. 183, no. 1, p. 19.

    Article  CAS  Google Scholar 

  2. Eddaoudi, M., Moler, D.B., Li, H., et al., Acc. Chem. Res., 2001, vol. 34, no. 4, p. 319.

    Article  CAS  Google Scholar 

  3. Hong, M.C., Cryst. Growth Des., 2007, vol. 7, no. 1, p. 10.

    Article  CAS  Google Scholar 

  4. Zhao, B., Cheng, P., Dai, Y., et al., Angew. Chem. Int. Ed., 2003, vol. 42, no. 8, p. 934.

    Article  CAS  Google Scholar 

  5. Fang, Q.R., Zhu, G.S., Xue, M., et al., Angew. Chem. Int. Ed., 2005, vol. 44, no. 25, p. 3845.

    Article  CAS  Google Scholar 

  6. Eddaoudi, M., Kim, J., Rosi, N., et al., Science, 2002, vol. 295, no. 5554, p. 469.

    Article  CAS  Google Scholar 

  7. Susumu, K., Ryo, K., and Shin-Ichiro, N., Angew. Chem. Int. Ed., 2004, vol. 43, no. 18, p. 2335.

    Google Scholar 

  8. Zhang, J.P. and Chen, X.M., Chem. Commun., 2006, no. 16, p. 1689.

  9. Wang, Y., Ding, B., Cheng, P., et al., Inorg. Chem., 2007, vol. 46, no. 6, p. 2002.

    Article  CAS  Google Scholar 

  10. Zhou, Y.F., Hong, M.C., and Wu, X.T., Chem. Commun., 2006, no. 1, p. 135.

  11. Wang, X.L., Qin, C., Wang, E.B., et al., Inorg. Chem., 2004, vol. 43, no. 6, p. 1850.

    Article  CAS  Google Scholar 

  12. Li, H., Eddaoudi, M., O’Keeffe, M., et al., Nature, 1999, vol. 402, no. 6759, p. 276.

    Article  CAS  Google Scholar 

  13. Zhao, B., Gao, H.L., Chen, X.Y., et al., Chem. Eur. J., 2005, vol. 12, no. 1, p. 149.

    Article  Google Scholar 

  14. Qin, C., Wang, X.L., Wang, E.B., et al., Inorg. Chim. Acta, 2006, vol. 359, no. 2, p. 417.

    Article  CAS  Google Scholar 

  15. Han, Z.B., Chen, X.N., Li, X.F., and Chen, X.M., Z. Anorg. Allg. Chem., 2005, vol. 631, no. 5, p. 937.

    Article  CAS  Google Scholar 

  16. Sheldrick, G.M., SHELXS-97, Program for X-Ray Crystal Structure Solution, Göttingen (Germany): Univ. of Göttingen, 1997

    Google Scholar 

  17. Sheldrick, G.M., SHELXS-97, Program for X-Ray Crystal Structure Refinement, Göttingen (Germany): Univ. of Göttingen, 1997.

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Laboratory of Coordination Chemistry, Shenyang Institute of Chemical Technology, Shenyang, 110142, R.P. China

    Y. G. Sun, X. F. Gu, E. J. Gao & W. Z. Zhang

  2. Department of Inorganic and Physical Chemistry, Ghent University, Ghent, 9000, Belgium

    F. Ding

Authors
  1. Y. G. Sun
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. X. F. Gu
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. F. Ding
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. E. J. Gao
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. W. Z. Zhang
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Y. G. Sun.

Additional information

The article is published in the original.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Sun, Y.G., Gu, X.F., Ding, F. et al. Synthesis, crystal structure, and magnetic properties of 2D coordination polymer “[Mn(PDB)(H2O)2] · H2O” n . Russ J Coord Chem 35, 916–919 (2009). https://doi.org/10.1134/S1070328409120100

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S1070328409120100

Keywords

Search

Navigation