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Synthesis and crystal structure of [Fe4O2(H2O)10(C5H5NCOO)4](NO3)8 · 2H2O

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Abstract

Crystals of the tetranuclear complex [Fe4O2(H2O)10(C5H5NCOO)4](NO3)8 · 2H2O are obtained by the slow evaporation of an aqueous solution of iron(III) nitrate and isonicotinic acid. According to the X-ray diffraction data, four metal atoms lie in the same plane and together with two μ3-O oxygen atoms form the fragment [Fe4(μ3-O)2]10+. The [Fe4O2(H2O)10(C5H5NCOO)4]8+ cation has been obtained and structurally characterized for the first time.

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Authors and Affiliations

  1. Nikolaev Institute of Inorganic Chemistry, Siberian Division, Russian Academy of Sciences, pr. Akad. Lavrent’eva 3, Novosibirsk, 630090, Russia

    E. A. Mainicheva, D. G. Samsonenko, O. A. Gerasko & V. P. Fedin

  2. Novosibirsk State University, ul. Pirogova 2, Novosibirsk, 630090, Russia

    D. G. Samsonenko & V. P. Fedin

Authors
  1. E. A. Mainicheva
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  2. D. G. Samsonenko
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  3. O. A. Gerasko
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  4. V. P. Fedin
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Correspondence to V. P. Fedin.

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Original Russian Text © E.A. Mainicheva, D.G. Samsonenko, O.A. Gerasko, V.P. Fedin, 2009, published in Koordinatsionnaya Khimiya, 2009, Vol. 35, No. 12, pp. 920–924.

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Mainicheva, E.A., Samsonenko, D.G., Gerasko, O.A. et al. Synthesis and crystal structure of [Fe4O2(H2O)10(C5H5NCOO)4](NO3)8 · 2H2O. Russ J Coord Chem 35, 908–911 (2009). https://doi.org/10.1134/S1070328409120082

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  • DOI: https://doi.org/10.1134/S1070328409120082

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