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Synthesis and crystal structure of (o-Diaminobenzene)2 Zn(OAc)2

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Abstract

The treatment of o-diaminobenzene with Zn ( OAc )2 · 2H2O in alcohol results in the formation of mononuclear bis(o-diaminobenzene)diacetate Zinc, Zn[C8H11N2O2]2. Its structure was determined by X-ray diffraction analysis. The complex is also characterized by elemental analysis, 1H NMR and IR. The crystal is monoclinic space group C2, parameters: a = 16.297(5), b = 4.775(3), c = 11.664(5) Å, β = 97.646(5)°, λ = 1.54184 Å, V = 899.6(7) Å3, Z = 2, ρ c = 1.476 g/cm3, M r = 399.75, F(000) = 416.0, R 1 = 0.0594, wR 2 = 0.1439 for 995 observed reflections with I > 2σ(I).

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References

  1. Chaudhuri, U.P., Whiteaker, L.R., Mondal, A., et al., Inorg. Chim. Acta, 2007, vol. 360, p. 3610.

    Article  Google Scholar 

  2. Singh, A.K., Kumari, S., and Kumar, K.R., Polyhedron, 2008, vol. 27, p. 181.

    Article  CAS  Google Scholar 

  3. Ali, M.A., Bakar, H.J.H.A., Mirza, A.H., and Smith, S.I. Polyhedron, 2008, vol. 27, p. 71.

    Article  CAS  Google Scholar 

  4. Wang, Z.M., Zhou, Z.F., Lin, H.K., et al., Chin. J. Inorg. Chem., 2000, vol. 16, p. 267.

    CAS  Google Scholar 

  5. Chen, F.T., Tang, G.R., and Jin, G.X., J. Org. Chem., 2007, vol. 692, p. 3435.

    Article  CAS  Google Scholar 

  6. Sumanta, K.P., Rojalin, S., and Vadivelu, M., Polyhedron, 2008, vol. 27, p. 805.

    Article  Google Scholar 

  7. Chakraborty, D. and Chen, E.Y.X., Organometallics, 2003, vol. 22, p. 769.

    Article  CAS  Google Scholar 

  8. Yu, K. and Jones, C.W., Organometallics, 2003, vol. 22, p. 2571.

    Article  CAS  Google Scholar 

  9. Sheldrick, G.M., SHELXS-97, Program for X-Ray Crystal Structure Solution, Göttingen (Germany): Univ. of Göttingen, 1997.

    Google Scholar 

  10. Sheldrick, G.M., SHELXL-97, Program for X-Ray Crystal Structure Refinement, Göttingen (Germany): Univ. of Göttingen, 1997.

    Google Scholar 

  11. Stout, G.H. and Jensen, L.H., X-Ray Structure Determination: a Practical Guide, New York: MacMillan, 1968.

    Google Scholar 

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Authors and Affiliations

  1. Hefei University of Technology, Hefei, 230009, P.R. China

    L. Mei, J. Li & L. X. Liang

  2. University of Science and Technology of China, Hefei, 230009, P.R. China

    Z. S. Ming & L. Q. Rong

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  1. L. Mei
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  2. J. Li
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  3. Z. S. Ming
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  4. L. Q. Rong
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  5. L. X. Liang
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Correspondence to L. Mei.

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Mei, L., Li, J., Ming, Z.S. et al. Synthesis and crystal structure of (o-Diaminobenzene)2 Zn(OAc)2 . Russ J Coord Chem 35, 871–873 (2009). https://doi.org/10.1134/S107032840912001X

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  • DOI: https://doi.org/10.1134/S107032840912001X

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