Skip to main content
SpringerLink
Log in

Molecular and crystal structures of [FeCl(HMPA)3(H2O)2]2+(FeCl4) −2 · 3HMPA

  • Published:
Russian Journal of Coordination Chemistry Aims and scope Submit manuscript

Abstract

IR and single-crystal X-ray diffraction study are carried out for compound, C36H112Cl9Fe3N18O8P6(I). It crystallizes in the orthorhombic space group P212121 with a = 14.2992(3), b = 21.4351(4), c = 25.5407(5) Å, V = 7828.3(3) Å3, ρcalcd = 1.553 g/cm3, Z = 4. The FeCl fragment is coordinated with chlorine atom of two water molecules and three HMPA molecules to form a cation, with a distorted octahedral coordinate geometry. In the crystal I, the cation is linked with HMPA by the O-H…O hydrogen bond. The chiral crystal is formed through self-assembly even from achiral molecules.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Hunter, C.A., Chem. Soc. Rev., 1994, vol. 23, p. 101.

    Article  CAS  Google Scholar 

  2. Molander, G.A. and Harris, C.R., Chem. Rev., 1996, vol. 96, p. 307.

    Article  CAS  Google Scholar 

  3. Hasegawa, E. and Currm, D.P., Tetrahedron Lett., 1993, vol. 34, p. 1717.

    Article  CAS  Google Scholar 

  4. Wiseman, T., Williston, S., Brandts, J.F., and Lin, L.N., Anal. Biochem., 1989, vol. 179, p. 131.

    Article  CAS  Google Scholar 

  5. Freire, E., Mayorga, O.L., and Straume, M., Anal. Chem., 1990, vol. 62, p. 950A.

    Article  CAS  Google Scholar 

  6. Morel-Desrosiers, N., Lhermet, C., and Morel, J.P.J., Faraday Trans., 1991, vol. 87, p. 2173.

    Article  CAS  Google Scholar 

  7. Koshima, H., Ding, K., Chisaka, Y., and Matsuura, T., J. Am. Chem. Soc., 1996, vol. 118, p. 12059.

    Article  CAS  Google Scholar 

  8. Farrugia, L.J., J. Appl. Crystallogr., 1999, vol. 32, p. 837.

    Article  Google Scholar 

  9. Sheldrick G.M., SHELXL-97, Göttingen (Germany): Univ. of Göttingen, 1997.

    Google Scholar 

  10. SHELXTL, Version 6.10, Madison (WI, USA): Bruker AXS Inc., 2003.

  11. Okuda, J., Fokken, S., Kleinhenn, T., and Spaniol, T.P., Eur. J. Inorg. Chem., 2000, p. 1321.

  12. Benson, M.K., Acta Crystallogr., C, 1995, vol. 51, p. 1051.

    Article  Google Scholar 

  13. Lough, A.J., Wheatley, P.S., Ferguson, G., and Glidewell, C., Acta Crystallogr., B, 2000, vol. 56, p. 261.

    Article  Google Scholar 

  14. Hou, Z. and Wakatsuki, Y.J., Chem. Commun., 1994, p. 1205.

Download references

Author information

Authors and Affiliations

  1. College of Pharmaceutical Sciences, Zhejiang University of Technology, Hangzhou, 310014, P.R. China

    Z. M. Jin, W. Xu, G. Chen & Z. Yang

Authors
  1. Z. M. Jin
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. W. Xu
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. G. Chen
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Z. Yang
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Z. M. Jin.

Additional information

The article is published in the original.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Jin, Z.M., Xu, W., Chen, G. et al. Molecular and crystal structures of [FeCl(HMPA)3(H2O)2]2+(FeCl4) −2 · 3HMPA. Russ J Coord Chem 35, 780–783 (2009). https://doi.org/10.1134/S1070328409100121

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S1070328409100121

Keywords

Search

Navigation