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Two octacyanomolybdate(IV)-M(II) (M = Mn, Co) bimetallic assemblies: Crystal structures and magnetic properties

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Abstract

Two cyano-bridged bimetallic complexes {[M2(H2O)4Mo(CN)8] · 4H2O} n [M = Mn (I) and Co (II)] have been synthesized and structurally characterized. The single-crystal X-ray analyses reveal that these two compounds have three-dimensional structures, and cell parameters are similar in a tetragonal system with space group I \( \bar 4 \). In the both complexes, each [Mo(CN)8]4− building block is linked with M2+ [M = Mn and Co] ions through its eight CN ligands. Each M2+ center is connected to four Mo units forming a three-dimensional framework. In addition, magnetic studies of these complexes have been presented.

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  1. Department of Application Chemistry, College of Science, Tianjin University of Commerce, Tianjin, 300134, P.R. China

    S. L. Ma & S. Ren

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  1. S. L. Ma
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  2. S. Ren
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Correspondence to S. L. Ma.

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Ma, S.L., Ren, S. Two octacyanomolybdate(IV)-M(II) (M = Mn, Co) bimetallic assemblies: Crystal structures and magnetic properties. Russ J Coord Chem 35, 766–771 (2009). https://doi.org/10.1134/S1070328409100091

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  • DOI: https://doi.org/10.1134/S1070328409100091

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